Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals

R Cauwenbergh, V Goyal, R Maiti, K Natte… - Chemical Society …, 2022 - pubs.rsc.org
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Visible‐Light‐Enabled Carboxylation of Benzyl Alcohol Derivatives with CO2 Using a Palladium/Iridium Dual Catalyst

Y Jin, N Toriumi, N Iwasawa - ChemSusChem, 2022 - Wiley Online Library
A highly efficient carboxylation of benzyl alcohol derivatives with CO2 using a
palladium/iridium dual catalyst under visible‐light irradiation was developed. A wide range …

Mechanistic Insight into Rh-Catalyzed C(sp2)–O Bond Cleavage Applied to Cross-Coupling Reaction of Benzofurans with Aryl Grignard Reagents

T Iwasaki, W Ishiga, S Pal, K Nozaki, N Kambe - ACS Catalysis, 2022 - ACS Publications
A mechanistic study of the Rh-catalyzed cross-coupling reaction of vinylic ethers with aryl
Grignard reagents via C (sp2)–O bond cleavage is reported herein. To obtain mechanistic …

Computational exploration of substrate and ligand effects in nickel-catalyzed C–Si bond carboxylation with CO 2

X Lv, X Zhang, R Sa, F Huang, G Lu - Organic Chemistry Frontiers, 2019 - pubs.rsc.org
The substrate and ligand effects in nickel-catalyzed C–Si bond carboxylation with CO2 were
investigated using density functional theory (DFT) calculations. Distortion/interaction …

Estudo computacional do mecanismo de acoplamento cruzado CC via dupla ativação das ligações CO de éteres catalisado por complexo de níquel

FVZ Assad - 2023 - teses.usp.br
A ativação ou clivagem da ligação CO é uma excelente estratégia para se promover
reações de acoplamento cruzado de eletrófilos oxigenados. Shi e Cao desenvolveram uma …

Coordination compounds of nickel, palladium, and platinum

A Zarkadoulas, CA Mitsopoulou - … and Photophysics of …, 2023 - books.google.com
Group 10 compounds of nickel, palladium, and platinum have been used as paradigms over
the years of evolution of inorganic chemistry, from early stages of chemical kinetics that …