Ionic-liquid-catalyzed approaches under metal-free conditions

Y Zhao, B Han, Z Liu - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Metal-free catalysis is a promising protocol to access chemicals without metal
contamination. Ionic liquids (ILs) that are entirely composed of organic cations and …

Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis

J Dupont, BC Leal, P Lozano, AL Monteiro… - Chemical …, 2024 - ACS Publications
Ionic liquids (ILs) have unique physicochemical properties that make them advantageous for
catalysis, such as low vapor pressure, non-flammability, high thermal and chemical …

[HTML][HTML] Solar-driven H 2 O 2 production via cooperative auto-and photocatalytic oxidation in fine-tuned reaction media

BC Moon, B Bayarkhuu, KAI Zhang, DK Lee… - Energy & …, 2022 - pubs.rsc.org
Solar photocatalysis has emerged as a sustainable route to produce H2O2; however, the
structural design of photocatalysts makes them expensive, limiting their practical …

[HTML][HTML] Basic ionic liquids for catalysis: the road to greater stability

P McNeice, PC Marr, AC Marr - Catalysis Science & Technology, 2021 - pubs.rsc.org
Basic ionic liquids can replace organic or inorganic bases in a wide range of reactions. In
this minireview the synthesis of homogeneous and heterogeneous basic ionic liquids and …

Metal-free activation of molecular oxygen by covalent triazine frameworks for selective aerobic oxidation

S Abednatanzi, P Gohari Derakhshandeh, K Leus… - Science …, 2020 - science.org
Oxygen activation is a critical step in ubiquitous heterogeneous oxidative processes, most
prominently in catalysis, electrolysis, and pharmaceutical applications. We present here our …

[PDF][PDF] Conjugation of sinapic acid analogues with 5-Fluorouracil: Synthesis, preliminary cytotoxicity, and release study

YF Mustafa, MK Oglah, MK Bashir - Systematic Reviews in …, 2020 - researchgate.net
Tripartite prodrug approach is a promising strategy to improve the therapeutic efficacy of
orally administrated drugs having a low bioavailability. 5-Fluorouracil is a primary …

Binding energy as driving force for controllable reconstruction of hydrogen bonds with molecular scissors

Y Luo, H Ma, S Zhang, D Zheng, P Che… - Journal of the …, 2020 - ACS Publications
Hydrogen bonds are one of the most important directional intermolecular interactions and
play key roles in chemical and biochemical systems, but there is still a lack of prediction and …

[HTML][HTML] Selective hydrogenation via precise hydrogen bond interactions on catalytic scaffolds

S Shi, P Yang, C Dun, W Zheng, JJ Urban… - Nature …, 2023 - nature.com
The active site environment in enzymes has been known to affect catalyst performance
through weak interactions with a substrate, but precise synthetic control of enzyme inspired …

Hydrogen‐Binding‐Initiated Activation of O− H Bonds on a Nitrogen‐Doped Surface for the Catalytic Oxidation of Biomass Hydroxyl Compounds

X Liu, Y Luo, H Ma, S Zhang, P Che… - Angewandte …, 2021 - Wiley Online Library
Hydrogen binding of molecules on solid surfaces is an attractive interaction that can be used
as the driving force for bond activation, material‐directed assembly, protein protection, etc …

Highly efficient oxidation of 5‐hydroxymethylfurfural to 2, 5‐furandicarboxylic acid with heteropoly acids and ionic liquids

R Chen, J Xin, D Yan, H Dong, X Lu… - ChemSusChem, 2019 - Wiley Online Library
Furandicarboxylic acid (FDCA) is regarded as an important bioderived substitute for
petrochemically derived terephthalic acid (PTA), which is widely applied in the polymer …