Thermodynamics of carbonates

AV Radha, A Navrotsky - Reviews in Mineralogy and …, 2013 - pubs.geoscienceworld.org
The goal of geologic CO2 sequestration is not just to pump large volumes of supercritical
carbon dioxide into underground repositories but to keep it there for hundreds to thousands …

Energetic and structural studies of amorphous Ca1− xMgxCO3· nH2O (0⩽ x⩽ 1)

AV Radha, A Fernandez-Martinez, Y Hu, YS Jun… - … et Cosmochimica Acta, 2012 - Elsevier
Early stage amorphous precursors provide a low energy pathway for carbonate
mineralization. Many natural deposits of carbonate minerals and biogenic calcium …

Magnetite authigenesis and the warming of early Mars

NJ Tosca, IAM Ahmed, BM Tutolo, A Ashpitel… - Nature …, 2018 - nature.com
The Curiosity rover has documented lacustrine sediments at Gale Crater, but how liquid
water became physically stable on the early Martian surface is a matter of significant debate …

Molecular Simulation of CO2- and CO3-Brine-Mineral Systems

LM Hamm, IC Bourg, AF Wallace… - … in Mineralogy and …, 2013 - pubs.geoscienceworld.org
Atomistic simulations—molecular dynamics (MD) and Monte Carlo (MC) simulations, ab
initio and density functional theory (DFT) calculations—have proved useful in gaining insight …

Fe (II)-carbonate precipitation kinetics and the chemistry of anoxic ferruginous seawater

CZ Jiang, NJ Tosca - Earth and Planetary Science Letters, 2019 - Elsevier
The chemical evolution of anoxic seawater is chronicled in part by the abundance of
sedimentary Fe minerals. Our view of the chemical state of the oceans throughout much of …

Characterization of corrosion scale formed on 3Cr steel in CO2-saturated formation water

S Guo, L Xu, L Zhang, W Chang, M Lu - Corrosion Science, 2016 - Elsevier
The evolution of the corrosion scale formed on 3Cr steel was investigated by scanning
electron microscopy (SEM) and X-Ray Diffraction (XRD). The inner layer was characterized …

Chromium (VI) removal by siderite (FeCO3) in anoxic aqueous solutions: An X-ray absorption spectroscopy investigation

I Bibi, NK Niazi, G Choppala, ED Burton - Science of the Total Environment, 2018 - Elsevier
Chromium (VI) is an environmental contaminant of priority concern, which can be treated by
reduction of toxic Cr (VI) to non-toxic Cr (III). Siderite (FeCO 3), an Fe (II)-containing mineral …

Time-resolved in situ raman spectroscopy of the nucleation and growth of siderite, magnesite, and calcite and their precursors

G Montes-Hernandez, F Renard - Crystal Growth & Design, 2016 - ACS Publications
The nucleation and growth processes of particles and crystals from aqueous systems are
actively investigated and occasionally open to debate because multistep nucleation and …

[HTML][HTML] Kinetic isotope effect in siderite growth: Implications for the origin of banded iron formation siderite

CZ Jiang, I Halevy, NJ Tosca - Geochimica et cosmochimica acta, 2022 - Elsevier
The widespread occurrence of siderite (FeCO 3) at Earth's modern surface and in
sedimentary rocks has led to its frequent use as a tool for palaeoenvironmental …

[HTML][HTML] Formation of diagenetic siderite in modern ferruginous sediments

A Vuillemin, R Wirth, H Kemnitz, AM Schleicher… - …, 2019 - pubs.geoscienceworld.org
Ferruginous conditions prevailed in the world's deep oceans during the Archean and
Proterozoic Eons. Sedimentary iron formations deposited at that time may provide an …