Conspectus Transition metal hydride catalyzed functionalization of remote and proximal
olefins has many advantages over conventional cross-coupling reactions. It avoids the …

Conspectus Recently, alkene dicarbofunctionalization, ie, the powerful organic synthesis
method of alkene difunctionalization with two carbon sources, emerged as a formidable …

1, 2-Dicarbofunctionalization of alkenes has emerged as an efficient synthetic strategy for
preparing substituted molecules by coupling readily available alkenes with electrophiles …

In the era of organic synthesis, the direct difunctionalization strategies of alkenes and
alkynes are very eminent, which open up an excellent route to introduce two functional …

Carboxylation of easily available alkenes with CO2 is highly important to afford value‐added
carboxylic acids. Although dicarboxylation of activated alkenes, especially 1, 3‐dienes, has …

Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …

Alkenes and alkynes are feedstock compounds and key units in many natural products,
pharmaceuticals, agrochemicals, and organic functional materials. Hydrofunctionalization …

This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

Three-component carboacylation of simple alkenes with readily available reagents is
challenging. Transition metal-catalysed intermolecular carboacylation works for alkenes with …

Site-and enantio-selective alkyl–alkyl bond formation is privileged in the retrosynthetic
analysis due to the universality of sp3-hybridized carbon atoms in organic molecules …