Synthesis of Dibenzosultams by “Transition-Metal-Free” Photoinduced Intramolecular Arylation of N-Aryl-2-halobenzenesulfonamides

WD Guerra, RA Rossi, AB Pierini… - The Journal of Organic …, 2016 - ACS Publications
A new and general synthetic route to prepare dibenzosultams is here reported. This
approach involves the synthesis of N-aryl-2-halobenzenesulfonamides (3), followed by …

Nucleophilic addition to singlet diradicals: homosymmetric diradicals

PG Wenthold, AH Winter - The Journal of Organic Chemistry, 2018 - ACS Publications
Experiments have demonstrated that nucleophiles can attack singlet diradicals to generate
bonded, closed-shell addition products. Here, we present a molecular orbital analysis for …

Nucleophilic addition to singlet diradicals: heterosymmetric diradicals

PG Wenthold, AH Winter - The Journal of Organic Chemistry, 2018 - ACS Publications
In the preceding paper, we examined the addition of nucleophiles to homosymmetric
diradicals and showed that the reaction occurs with no symmetry restrictions or other …