Addition to C= N bonds with acyclic stereocontrol offers excellent potential for development
of new carbon–carbon bond construction approaches to chiral amines. This review features …

Cyclizative Atmospheric CO2 Fixation by Unsaturated Amines with t-BuOI Leading to Cyclic
Carbamates | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In …

Isatin (1H-indole-2, 3-dione, Figure 1) was first obtained by Erdman and Laurent in 1841 as
a product from the oxidation of indigo by nitric and chromic acids. 1 Since then, isatin and its …

Described is a new hydrazone‐based exo‐directing group (DG) strategy developed for the
functionalization of unactivated primary β C− H bonds of aliphatic amines. Conveniently …

This chapter deals with the formation of carbon‐nitrogen bonds by reaction of carbon
nucleophiles with electrophilic aminating reagents. The former encompass aliphatic and …

The incorporation of difluoromethylene (CF2) group into chemical molecules often imparts
desirable properties such as lipophilicity, binding affinity, and thermal stability …

A survey of several electrophilic ammonia reagents for the N-amination of indole-and pyrrole-
containing heterocycles revealed that monochloramine (NH2Cl) is an excellent reagent for …

Synthesis of γ-amino acids, important building blocks in bioorganic and natural product
chemistry, is accomplished using a stereoselective carbon− carbon bond construction of the …

The unique reactivity profile of α-chloronitroso derivatives is expressed to its fullest potential
through the development of an integrated, modular and scalable continuous flow process for …

A palladium-catalyzed, enantioselective, aryl–aryl cross-coupling reaction using 1-
naphthyldimethylsilanolates and chiral bis-hydrazone ligands has been developed. A family …