Advances in heterogeneous single-cluster catalysis

X Li, S Mitchell, Y Fang, J Li, J Perez-Ramirez… - Nature Reviews …, 2023 - nature.com
Heterogeneous single-cluster catalysts (SCCs) comprising atomically precise and isolated
metal clusters stabilized on appropriately chosen supports offer exciting prospects for …

State of the art and perspectives in heterogeneous catalysis of CO 2 hydrogenation to methanol

J Zhong, X Yang, Z Wu, B Liang, Y Huang… - Chemical Society …, 2020 - pubs.rsc.org
The ever-increasing amount of anthropogenic carbon dioxide (CO2) emissions has resulted
in great environmental impacts. The selective hydrogenation of CO2 to methanol, the first …

Comprehensive review of Cu-based CO2 hydrogenation to CH3OH: Insights from experimental work and theoretical analysis

J Niu, H Liu, Y Jin, B Fan, W Qi, J Ran - International Journal of Hydrogen …, 2022 - Elsevier
Developing the technology of CO 2 hydrogenation into methanol can not only alleviate
environmental problems such as greenhouse effect, but also effectively promote the …

Advances in the Design of Heterogeneous Catalysts and Thermocatalytic Processes for CO2 Utilization

S De, A Dokania, A Ramirez, J Gascon - ACS Catalysis, 2020 - ACS Publications
Utilization of CO2 as feedstock to produce fine chemicals and renewable fuels is a highly
promising field, which presents unique challenges in its implementation at scale …

Strong Electronic Oxide–Support Interaction over In2O3/ZrO2 for Highly Selective CO2 Hydrogenation to Methanol

C Yang, C Pei, R Luo, S Liu, Y Wang… - Journal of the …, 2020 - ACS Publications
Metal oxides are widely employed in heterogeneous catalysis, but it remains challenging to
determine their exact structure and understand the reaction mechanisms at the molecular …

Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface

S Kattel, P Liu, JG Chen - Journal of the American Chemical …, 2017 - ACS Publications
The chemical transformation of CO2 not only mitigates the anthropogenic CO2 emission into
the Earth's atmosphere but also produces carbon compounds that can be used as …

Copper nanoclusters: designed synthesis, structural diversity, and multiplatform applications

A Baghdasaryan, T Bürgi - Nanoscale, 2021 - pubs.rsc.org
Atomically precise metal nanoclusters (MNCs) have gained tremendous research interest in
recent years due to their extraordinary properties. The molecular-like properties that …

Scalable synthesis of Cu clusters for remarkable selectivity control of intermediates in consecutive hydrogenation

D Yao, Y Wang, Y Li, A Li, Z Zhen, J Lv, F Sun… - Nature …, 2023 - nature.com
Subnanometric Cu clusters that contain only a small number of atoms exhibit unique and,
often, unexpected catalytic behaviors compared with Cu nanoparticles and single atoms …

An overview of Cu-based heterogeneous electrocatalysts for CO 2 reduction

J Zhao, S Xue, J Barber, Y Zhou, J Meng… - Journal of Materials …, 2020 - pubs.rsc.org
The electrochemical (EC) reduction of CO2 is a promising approach for value-added fuel or
chemical production. Cu-based electrodes have been extensively used as a 'star'material for …

Advances of atomically dispersed catalysts from single-atom to clusters in energy storage and conversion applications

Y Wang, X Cui, J Zhang, J Qiao, H Huang, J Shi… - Progress in Materials …, 2022 - Elsevier
Owing to the special structural characteristics and maximized efficiency, atomically
dispersed catalysts (ADCs) with different atom sizes ranged from the single atom to clusters …