Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications

MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds

S Rej, Y Ano, N Chatani - Chemical reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Installing the “magic methyl”–C–H methylation in synthesis

D Aynetdinova, MC Callens, HB Hicks… - Chemical Society …, 2021 - pubs.rsc.org
The selective and efficient C–H methylation of sp2 and sp3 carbon centres has become a
powerful transformation in the synthetic toolbox. Due to the potential for profound changes to …

Iron-catalyzed C–H bond activation

R Shang, L Ilies, E Nakamura - Chemical Reviews, 2017 - ACS Publications
Catalytic C–H bond activation, which was an elusive subject of chemical research until the
1990s, has now become a standard synthetic method for the formation of new C–C and C …

Recent advances in chelation-assisted site-and stereoselective alkenyl C–H functionalization

J Zhang, X Lu, C Shen, L Xu, L Ding… - Chemical Society …, 2021 - pubs.rsc.org
Olefinic C–H functionalization represents an atom-and step economic approach to valuable
olefin derivatives from simpler ones, but controlling the selectivity remains a challenge …

Chelation-Assisted Iron-Catalyzed C–H Activations: Scope and Mechanism

J Mo, AM Messinis, J Li, S Warratz… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus To improve the resource economy of molecular syntheses, researchers have
developed strategies to directly activate otherwise inert C–H bonds, thus avoiding …

Iron-catalyzed C–H functionalization processes

G Cera, L Ackermann - Ni-and Fe-Based Cross-Coupling Reactions, 2017 - Springer
Iron-catalyzed C–H activation has recently emerged as an increasingly powerful tool for the
step-economical transformation of unreactive C–H bonds. Particularly, the recent …