Acetalization strategy in biomass valorization: a review

J He, Q Qiang, L Bai, W Su, H Yu, S Liu… - Industrial Chemistry & …, 2024 - pubs.rsc.org
Acetalization represents an appealing approach for the valorization of biobased platform
molecules into valuable chemicals and fuels. Typically, it serves as both a synthesis tool for …

Toward understanding base-catalyzed isomerization of saccharides

I Delidovich - Acs Catalysis, 2023 - ACS Publications
This Perspective addresses recent advances in isomerization of aldoses into ketoses
catalyzed by bases. In recent years, catalytic activity of a number of bases was reported, but …

Integration of Deep Eutectic Solvents and Hydrotalcites for Biomass Conversion and Aldol Condensation: Toward Platform Chemicals and Jet Fuel Synthesis—A …

R Ceaser, D Montané, F Medina… - ChemBioEng …, 2024 - Wiley Online Library
The abundance and renewability of lignocellulosic biomass have made it a suitable
alternative to fossil fuels in the reduction of global warming. The complex nature of the …

Study of base-catalyzed isomerization of d-glucose with a focus on reaction kinetics

M Fischer, P Drabo, I Delidovich - Reaction Kinetics, Mechanisms and …, 2022 - Springer
We explored the isomerization of d-glucose into d-fructose using the simplest possible base
catalyst, aqueous NaOH, to maintain a constant pH value during the reaction. Under the …

Thermodynamic Insights into MgBr2-Mediated Glucose Interconversion to Fructose Undertaking Multiple Reaction Pathways by Applying the Macro- and Micro …

B Devi, SM Arumugam, S Kumar… - ACS Sustainable …, 2023 - ACS Publications
While many reports on the kinetics and mechanism of glucose isomerization to fructose via a
chemical pathway have been published, thermodynamic insights into the interconversion …

Isomerization of Hemicellulose Aldoses to Ketoses Catalyzed by Basic Anion Resins: Catalyst Screening and Stability Studies

M El Tawil-Lucas, M Montaña, M Macias-Villasevil… - Catalysts, 2023 - mdpi.com
Isomerization of aldoses to ketoses is an essential step in carbohydrate valorization routes
in biorefineries to produce a wide variety of bioproducts. In this work, selective isomerization …

[HTML][HTML] Li-promoted C3N4 catalyst for efficient isomerization of glucose into fructose at 50° C in water

W Liu, Y Zhang, M Sun, X Zhao, S Li, X Chen… - Green Energy & …, 2024 - Elsevier
Efficient and selective glucose-to-fructose isomerization is a crucial step for production of
oxygenated chemicals derived from sugars, which is usually catalyzed by base or Lewis …

Flow Semi-continuous Mechanochemistry as a Versatile and Efficient Tool for the Synthesis of Hydrocalumite and the Isomerization of Glucose to Fructose

AM Pérez-Merchán, R Moreno-Tost, I Malpartida… - Topics in …, 2024 - Springer
In this work, hydrocalumite, a layered double hydroxide with formula Ca2Al (OH) 6Cl· 2H2O,
has been prepared for the first time using flow semi-continuous mechanochemistry with a …

Tuning of MgO's base characteristics by blending it with amphoteric ZnO facilitating the selective glucose isomerization to fructose for bioenergy development

S Mahala, SM Arumugam, S Kumar, B Devi… - Nanoscale …, 2023 - pubs.rsc.org
Fructose serves as an important intermediate in the preparation of liquid fuel compounds.
Herein, we report its selective production via a chemical catalysis method over ZnO/MgO …

Enhanced Catalytic Activity of Modified ZSM‐5 Towards Glucose Isomerization to Fructose

R Gautam, P Pal, S Saravanamurugan - ChemPlusChem, 2023 - Wiley Online Library
The present study focuses on generating mesopores within H− ZSM‐5 (H− Z) zeolite via
desilication and dealumination to incorporate Lewis acidic metal, such as Sn, into the …