Dynamic bonds: adaptable timescales for responsive materials

SV Wanasinghe, OJ Dodo… - Angewandte Chemie, 2022 - Wiley Online Library
Dynamic bonds introduce unique properties such as self‐healing, recyclability, shape
memory, and malleability to polymers. Significant efforts have been made to synthesize a …

Synthesis and applications of boronic acid-containing polymers: from materials to medicine

WLA Brooks, BS Sumerlin - Chemical reviews, 2016 - ACS Publications
Recently, boronic acid-containing macromolecules have been utilized in a number of
biomedical applications, 1 including use in dynamic covalent materials, dual thermo-and …

Advances in applied supramolecular technologies

GT Williams, CJE Haynes, M Fares… - Chemical Society …, 2021 - pubs.rsc.org
Supramolecular chemistry is a comparatively young field that to date has mainly been
focused on building a foundation of fundamental understanding. With much progress in this …

Malleable and self-healing covalent polymer networks through tunable dynamic boronic ester bonds

OR Cromwell, J Chung, Z Guan - Journal of the American …, 2015 - ACS Publications
Despite numerous strategies involving dynamic covalent bond exchange for dynamic and
self-healing materials, it remains a challenge to be able to tune the malleability and self …

Neighboring group participation and internal catalysis effects on exchangeable covalent bonds: application to the thriving field of vitrimer chemistry

F Cuminet, S Caillol, É Dantras, E Leclerc… - …, 2021 - ACS Publications
Vitrimers constitute a fascinating class of polymer materials that make the link between the
historically opposed 3D networks (thermosets) and linear polymers (thermoplastics). Their …

Bulk network polymers with dynamic B–O bonds: Healable and reprocessable materials

AP Bapat, BS Sumerlin, A Sutti - Materials Horizons, 2020 - pubs.rsc.org
The need to minimize the amount of polymeric waste entering landfills and oceans has led
to several research avenues in the field of polymer science. Particularly, the development of …

Glucose sensing in supramolecular chemistry

X Sun, TD James - Chemical Reviews, 2015 - ACS Publications
The world is made up of fundamental elements, ions and molecules that continuously
interact with each other through a series of chemical reactions. Thus, it is important to have a …

The mechanisms of boronate ester formation and fluorescent turn-on in ortho-aminomethylphenylboronic acids

X Sun, BM Chapin, P Metola, B Collins, B Wang… - Nature …, 2019 - nature.com
Abstract ortho-Aminomethylphenylboronic acids are used in receptors for carbohydrates and
various other compounds containing vicinal diols. The presence of the o-aminomethyl group …

Structure–reactivity relationships in boronic acid–diol complexation

WLA Brooks, CC Deng, BS Sumerlin - ACS omega, 2018 - ACS Publications
Boronic acids have found widespread use in the field of biomaterials, primarily through their
ability to bind with biologically relevant 1, 2-and 1, 3-diols, including saccharides and …

Boronic acid building blocks: tools for self assembly

R Nishiyabu, Y Kubo, TD James… - Chemical …, 2011 - pubs.rsc.org
Dynamic covalent functionality has been acknowledged as a powerful tool for the
construction of organised architectures, the reversible nature thermodynamically facilitates …