Flexible Metal–Organic Frameworks: From Local Structural Design to Functional Realization

N Li, J Pang, F Lang, XH Bu - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Flexible metal–organic frameworks (MOFs), also known as soft porous crystals,
exhibit dynamic behaviors in response to external physical and chemical stimuli such as …

Tetrazine-based metal-organic frameworks

H Jiang, Q Gong, R Zhang, H Yuan - Coordination Chemistry Reviews, 2024 - Elsevier
Abstract Metal-organic frameworks (MOFs), featuring tailor-made structural topology and
porosity (aperture size and geometry) by judicious choices of inorganic second building …

Highly Selective p-Xylene Separation from Mixtures of C8 Aromatics by a Nonporous Molecular Apohost

M Rahmani, CRMO Matos, SQ Wang… - Journal of the …, 2023 - ACS Publications
High and increasing production of separation of C8 aromatic isomers demands the
development of purification methods that are efficient, scalable, and inexpensive, especially …

Metal–Organic Frameworks for Highly Selective Separation of Xylene Isomers and Single-Crystal X-ray Study of Aromatic Guest–Host Inclusion Compounds

AA Sapianik, ER Dudko, KA Kovalenko… - … applied materials & …, 2021 - ACS Publications
Separation of hydrocarbon molecules, such as benzene/cyclohexane and o-xylene/m-
xylene/p-xylene, is relevant due to their widespread application as chemical feedstock but …

Structural phase transformations induced by guest molecules in a nickel-based 2D Square lattice coordination network

X Li, D Sensharma, VI Nikolayenko… - Chemistry of …, 2023 - ACS Publications
Herein, we report the crystal structure and guest binding properties of a new two-
dimensional (2D) square lattice (sql) topology coordination network, sql-(azpy)(pdia)-Ni …

Kinetic trapping of 2,4,6-tris(4-pyridyl)benzene and ZnI2 into M12L8 poly-[n]-catenanes using solution and solid-state processes

J Martí-Rujas, S Elli, A Famulari - Scientific Reports, 2023 - nature.com
Here, we show that in a supramolecular system with more than 20 building blocks forming
large icosahedral M 12 L 8 metal–organic cages (MOCs), using the instant synthesis …

A gating ultramicroporous metal-organic framework showing high adsorption selectivity, capacity and rate for xylene separation

ZM Ye, XF Zhang, DX Liu, YT Xu, C Wang… - Science China …, 2022 - Springer
Adsorptive separation of p-xylene (p X) from xylene isomers is a key process in chemical
industry, but known adsorbents cannot simultaneously achieve high adsorption selectivity …

Switching Adsorbent Layered Material that Enables Stepwise Capture of C8 Aromatics via Single-Crystal-to-Single-Crystal Transformations

MY Gao, SQ Wang, AA Bezrukov, S Darwish… - Chemistry of …, 2023 - ACS Publications
Separation of the C8 aromatic isomers, xylenes (PX, MX, and OX) and ethylbenzene (EB), is
important to the petrochemical industry. Whereas physisorptive separation is an energy …

Water vapour and gas induced phase transformations in an 8-fold interpenetrated diamondoid metal–organic framework

A Subanbekova, VI Nikolayenko… - Journal of Materials …, 2023 - pubs.rsc.org
In this work, we report the synthesis, structural characterisation and sorption properties of an
8-fold interpenetrated diamondoid (dia) metal–organic framework (MOF) that is sustained by …

Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures

AN Bilyachenko, GS Astakhov, AN Kulakova… - Crystal Growth & …, 2022 - ACS Publications
Within the sweeping research on the design of new coordination polymers and related metal–
organic architectures, the use of silsesquioxane derivatives as important organosilicon …