Photo‐iniferter RAFT polymerization

M Hartlieb - Macromolecular Rapid Communications, 2022 - Wiley Online Library
Light‐mediated polymerization techniques offer distinct advantages over polymerization
reactions fueled by thermal energy, such as high spatial and temporal control as well as the …

RAFT polymerization to form stimuli-responsive polymers

G Moad - Polymer Chemistry, 2017 - pubs.rsc.org
Stimuli-responsive polymers adapt to their surrounding environment. These polymers are
capable of responding to a variety of external stimuli, which include optical, electrical …

[HTML][HTML] Radical-promoted single-unit monomer insertion (SUMI)[aka. reversible-deactivation radical addition (RDRA)]

C Boyer, M Kamigaito, K Satoh, G Moad - Progress in Polymer Science, 2023 - Elsevier
We survey progress in the development of the processes for radical-promoted single-unit
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …

Single unit monomer insertion: a versatile platform for molecular engineering through radical addition reactions and polymerization

J Xu - Macromolecules, 2019 - ACS Publications
Single unit monomer insertion (SUMI) is an emerging technology for precise polymer
synthesis through a radical addition reaction mechanism with monomer additions occurring …

End-functionalized polymers by controlled/living radical polymerizations: synthesis and applications

D Zhou, LW Zhu, BH Wu, ZK Xu, LS Wan - Polymer Chemistry, 2022 - pubs.rsc.org
The precise design of polymers with well-defined end functionality has received great
interest for synthesizing polymeric materials with advanced or distinctive properties. In the …

The challenges of controlling polymer synthesis at the molecular and macromolecular level

K Hakobyan, J Xu, M Müllner - Polymer Chemistry, 2022 - pubs.rsc.org
Modern applications of polymers demand further elaboration of molecular-level structures as
well as control of various macro-level features. There have been significant advances …

Bottom-up strategies for the synthesis of peptide-based polymers

J Martin, A Desfoux, J Martinez, M Amblard… - Progress in Polymer …, 2021 - Elsevier
Thanks to their wide range of biological activities, peptides have been extensively used to
afford designed materials with tailored properties. Peptides can be associated to polymers …

Sequential and alternating RAFT single unit monomer insertion: model trimers as the guide for discrete oligomer synthesis

R Liu, L Zhang, Z Huang, J Xu - Polymer Chemistry, 2020 - pubs.rsc.org
Sequence-defined polymers have garnered increasing attention in a broad range of
applications from materials engineering to medical science. Reversible addition …

Trithiocarbonates in RAFT polymerization

G Moad - RAFT Polymerization: Methods, Synthesis and …, 2021 - Wiley Online Library
This chapter provides a review of the synthesis, reactions, and applications of
trithiocarbonates, R′ SC ( S) SR, in radical polymerization with reversible addition …

Synthesis and applications of protein/peptide‐polymer conjugates

P Wilson - Macromolecular Chemistry and Physics, 2017 - Wiley Online Library
Recent advances in synthetic methodologies have brought us closer than ever to the
precision conferred by nature. For example, the control possible in reversible deactivation …