Hydrodeoxygenation of potential platform chemicals derived from biomass to fuels and chemicals

K Tomishige, M Yabushita, J Cao, Y Nakagawa - Green Chemistry, 2022 - pubs.rsc.org
Biomass valorization has emerged as a promising and sustainable means of
accommodating value-added chemicals. To produce such chemicals, various transformation …

Bio-based 1, 4-butanediol and tetrahydrofuran synthesis: perspective

Y Zhu, J Yang, F Mei, X Li, C Zhao - Green Chemistry, 2022 - pubs.rsc.org
1, 4-Butanediol (1, 4-BDO) and tetrahydrofuran (THF) are important feedstocks for the
synthesis of polyurethane elastomers, polybutylene succinate (PBS), polybutylene …

Selective C–C and C–O bond cleavage strategies for the thermochemical upgrading of (hemi) cellulosic biomass

R Sun, C Yang, Z Fang, N Zhu, M Zheng, K Guo… - Applied Catalysis B …, 2024 - Elsevier
Utilizing lignocellulose as an alternative green carbon resource is recognized as a vital
approach to drive the ongoing transition towards a sustainable manufacture of chemicals …

Green solvent free epoxidation of olefins by a heterogenised hydrazone-dioxidotungsten (VI) coordination compound

N Heydari, R Bikas, M Shaterian, T Lis - RSC advances, 2022 - pubs.rsc.org
A new mononuclear tungsten coordination compound,[WO2L (CH3OH)](1), was synthesized
by the reaction of WCl6 and H2L (H2L=(E)-4-amino-N′-(5-bromo-2-hydroxybenzylidene) …

Dynamic Formation of Brønsted Acid Sites over Supported WOx/Pt on SiO2 Inverse Catalysts─Spectroscopy, Probe Chemistry, and Calculations

Y Wu, S Sourav, A Worrad, J Zhou, S Caratzoulas… - ACS …, 2023 - ACS Publications
Platinum-tungsten oxides are among the most studied metal–metal oxide pair catalysts for C–
O hydrogenolysis reactions. The Brønsted acid density and synergy between Pt and WO x …

Highly Efficient Iridium–Iron–Molybdenum Catalysts Condensed on Boron Nitride for Biomass-Derived Diols' Hydrogenolysis to Secondary Monoalcohols

B Liu, Y Nakagawa, M Yabushita… - Journal of the American …, 2024 - ACS Publications
A trade-off of activity–selectivity exists in primary C–O hydrogenolysis of biomass-derived
diols to secondary alcohols over bimetallic catalysts, especially the combination of noble …

Biphasic solvent systems enabled lignocellulosic biomass fractionation: A pathway towards comprehensive biomass utilization

B Gao, C Sun, T Yang, Q Wen, S You, Q Yang… - Industrial Crops and …, 2023 - Elsevier
Lignocellulosic biomass is mainly composed of cellulose, hemicellulose and lignin, which
can be valorized into myriad fuels and chemicals. Most developed processes for its …

Utilization of Ni as a non-noble-metal co-catalyst for ceria-supported rhenium oxide in combination of deoxydehydration and hydrogenation of vicinal diols

K Yamaguchi, Y Nakagawa, C Li, M Yabushita… - ACS …, 2022 - ACS Publications
Removal of vicinal diols by combination of deoxydehydration and hydrogenation (DODH+
HG) was carried out over the mixture of ReO x/CeO2 and CeO2-supported base metals with …

Supported bifunctional molybdenum oxide-palladium catalysts for selective hydrodeoxygenation of biomass-derived polyols and 1, 4-anhydroerythritol

S Albarracin-Suazo… - ACS Sustainable …, 2022 - ACS Publications
Selective removal of oxygen from biomass-derived polyols is critical toward bridging the gap
between biomass feedstocks and the production of commodity chemicals. In this work, we …

Tuning the Surface Alloy Composition of Phosphorus-Promoted Ni–Co Bimetallic Nanoparticles for Selective Tandem Hydrogenation

D Ji, P Guo, Y Xi, J Li, J Wang, T Wang, F Li - ACS Catalysis, 2023 - ACS Publications
Selective tandem hydrogenation is a promising strategy for catalytic conversion of bulk raw
materials with multifunctional groups into high-value-added chemicals via multiple-step …