Electrochemistry and photoluminescence of icosahedral carboranes, boranes, metallacarboranes, and their derivatives

R Núñez, M Tarrés, A Ferrer-Ugalde… - Chemical …, 2016 - ACS Publications
Icosahedral boranes, carboranes, and metallacarboranes are extraordinarily robust
compounds with desirable properties such as thermal and redox stability, chemical …

Recent Progress in the Development of Solid‐State Luminescent o‐Carboranes with Stimuli Responsivity

J Ochi, K Tanaka, Y Chujo - Angewandte Chemie International …, 2020 - Wiley Online Library
Abstract o‐Carborane, a cluster compound containing boron and adjacent carbon atoms,
displays intriguing luminescent properties. Recently, compounds containing o‐carborane …

Boron clusters in luminescent materials

S Mukherjee, P Thilagar - Chemical Communications, 2016 - pubs.rsc.org
In recent times, luminescent materials with tunable emission properties have found
applications in almost all aspects of modern material sciences. Any discussion on the recent …

Tris(ortho‐carboranyl)borane: An Isolable, Halogen‐Free, Lewis Superacid

MO Akram, JR Tidwell, JL Dutton… - Angewandte …, 2022 - Wiley Online Library
The synthesis of tris (ortho‐carboranyl) borane (BoCb3), a single site neutral Lewis
superacid, in one pot from commercially available materials is achieved. The high fluoride …

Lewis acidity of boron compounds

IB Sivaev, VI Bregadze - Coordination Chemistry Reviews, 2014 - Elsevier
The effects of different electronic and structural factors in determining the Lewis acidity of
boron compounds are analyzed. Scales of Lewis acidity for boron Lewis acids based on the …

Chemodosimeters for optical detection of fluoride anion

S Dhiman, M Ahmad, N Singla, G Kumar… - Coordination Chemistry …, 2020 - Elsevier
Chemodosimeters–the reaction based sensing systems for F− ions provide the significantly
higher selectivity due to specificity of their reactions and also better opportunities for analysis …

Analytical methods for determination and sensing of fluoride in biotic and abiotic sources: a review

A Dhillon, M Nair, D Kumar - Analytical Methods, 2016 - pubs.rsc.org
Detection and characterization of fluoride is an important part of understanding the benefits
as well as the potential toxicity of fluoride in biotic and abiotic natural sources. Fluoride can …

The Effect of Carborane Substituents on the Lewis Acidity of Boranes

MO Akram, CD Martin, JL Dutton - Inorganic Chemistry, 2023 - ACS Publications
The Lewis acidity of primary, secondary, and tertiary boranes with phenyl,
pentafluorophenyl, and all three isomers of the C-substituted icosahedral carboranes (ortho …

Nido‐Carboranes: Donors for Thermally Activated Delayed Fluorescence

NV Nghia, S Jana, S Sujith, JY Ryu… - Angewandte Chemie …, 2018 - Wiley Online Library
An approach to the design of nido‐carborane‐based luminescent compounds that can
exhibit thermally activated delayed fluorescence (TADF) is proposed. 7, 8‐Dicarba‐nido …

Deep Red Phosphorescence of Cyclometalated Iridium Complexes by o-Carborane Substitution

HJ Bae, J Chung, H Kim, J Park, KM Lee… - Inorganic …, 2014 - ACS Publications
Heteroleptic (C∧ N) 2Ir (acac)(C∧ N= 5-MeCBbtp (5a); 4-BuCBbtp (5b); 5-BuCBbtp (5c); 5-
(R) CBbtp= 2-(2′-benzothienyl)-5-(2-R-ortho-carboran-1-yl)-pyridinato-C2, N, R= Me and n …