[HTML][HTML] Addressing complexity in catalyst design: From volcanos and scaling to more sophisticated design strategies

SM Stratton, S Zhang, MM Montemore - Surface Science Reports, 2023 - Elsevier
Volcano plots and scaling relations are commonly used to design catalysts and understand
catalytic behavior. These plots are a useful tool due to their robust and simple analysis of …

Application of 1D/2D carbon material supported metal nanoclusters for electrochemical conversion

Z Song, H Shi, L Liu, M Zeng, S Wang, X Wu… - Catalysis Science & …, 2024 - pubs.rsc.org
Metal nanoclusters (MNCs) are important in electrocatalysis, characterized by high atom
utilization, unique geometrical and electronic structures, and abundant active sites …

Fabrication of Large-Area Metal-on-Carbon Catalytic Condensers for Programmable Catalysis

KR Oh, TM Onn, A Walton, ML Odlyzko… - … Applied Materials & …, 2023 - ACS Publications
Catalytic condensers stabilize charge on either side of a high-k dielectric film to modulate
the electronic states of a catalytic layer for the electronic control of surface reactions. Here …

Generalized principles for the descriptor-based design of supported gold catalysts

L Rekhi, QT Trinh, AM Prabhu, TS Choksi - ACS Catalysis, 2024 - ACS Publications
We postulate generalized principles for determining catalytic descriptors like the adsorption
energy of CO*, across interfacial active sites of gold catalysts having varying coordination …

Electrically driven proton transfer promotes Brønsted acid catalysis by orders of magnitude

KS Westendorff, MJ Hülsey, TS Wesley… - Science, 2024 - science.org
Electric fields play a key role in enzymatic catalysis and can enhance reaction rates by
100,000-fold, but the same rate enhancements have yet to be achieved in thermochemical …

Flexible and Extensive Platinum Ion Gel Condensers for Programmable Catalysis

TM Onn, KR Oh, DZ Adrahtas, JK Soeherman… - ACS …, 2023 - ACS Publications
Catalytic condensers composed of ion gels separating a metal electrode from a platinum-on-
carbon active layer were fabricated and characterized to achieve more powerful, high …

Writing the programs of programmable catalysis

YM Psarellis, ME Kavousanakis, PJ Dauenhauer… - ACS …, 2023 - ACS Publications
It has long been known that non-steady state and periodic catalytic reactor operation in
terms of temperature, pressure, and composition can lead to higher overall productivity …

Energy flows in static and programmable catalysts

OA Abdelrahman, PJ Dauenhauer - ACS Energy Letters, 2023 - ACS Publications
Programmable catalysts that change on the time scale of a catalytic cycle provide a new
opportunity to control the flow of energy to reactants and products to promote faster and …

Catalytic resonance theory: the catalytic mechanics of programmable ratchets

MA Murphy, SR Gathmann, R Getman, L Grabow… - Chemical …, 2024 - pubs.rsc.org
Catalytic reaction networks of multiple elementary steps operating under dynamic conditions
via a programmed input oscillation are difficult to interpret and optimize due to reaction …

Dynamic Promotion of the Oxygen Evolution Reaction via Programmable Metal Oxides

SR Gathmann, CJ Bartel, LC Grabow… - ACS Energy …, 2024 - ACS Publications
Hydrogen gas is a promising renewable energy storage medium when produced via water
electrolysis, but this process is limited by the sluggish kinetics of the anodic oxygen …