[HTML][HTML] Addressing complexity in catalyst design: From volcanos and scaling to more sophisticated design strategies
Volcano plots and scaling relations are commonly used to design catalysts and understand
catalytic behavior. These plots are a useful tool due to their robust and simple analysis of …
catalytic behavior. These plots are a useful tool due to their robust and simple analysis of …
Application of 1D/2D carbon material supported metal nanoclusters for electrochemical conversion
Z Song, H Shi, L Liu, M Zeng, S Wang, X Wu… - Catalysis Science & …, 2024 - pubs.rsc.org
Metal nanoclusters (MNCs) are important in electrocatalysis, characterized by high atom
utilization, unique geometrical and electronic structures, and abundant active sites …
utilization, unique geometrical and electronic structures, and abundant active sites …
Fabrication of Large-Area Metal-on-Carbon Catalytic Condensers for Programmable Catalysis
Catalytic condensers stabilize charge on either side of a high-k dielectric film to modulate
the electronic states of a catalytic layer for the electronic control of surface reactions. Here …
the electronic states of a catalytic layer for the electronic control of surface reactions. Here …
Generalized principles for the descriptor-based design of supported gold catalysts
We postulate generalized principles for determining catalytic descriptors like the adsorption
energy of CO*, across interfacial active sites of gold catalysts having varying coordination …
energy of CO*, across interfacial active sites of gold catalysts having varying coordination …
Electrically driven proton transfer promotes Brønsted acid catalysis by orders of magnitude
Electric fields play a key role in enzymatic catalysis and can enhance reaction rates by
100,000-fold, but the same rate enhancements have yet to be achieved in thermochemical …
100,000-fold, but the same rate enhancements have yet to be achieved in thermochemical …
Flexible and Extensive Platinum Ion Gel Condensers for Programmable Catalysis
Catalytic condensers composed of ion gels separating a metal electrode from a platinum-on-
carbon active layer were fabricated and characterized to achieve more powerful, high …
carbon active layer were fabricated and characterized to achieve more powerful, high …
Writing the programs of programmable catalysis
YM Psarellis, ME Kavousanakis, PJ Dauenhauer… - ACS …, 2023 - ACS Publications
It has long been known that non-steady state and periodic catalytic reactor operation in
terms of temperature, pressure, and composition can lead to higher overall productivity …
terms of temperature, pressure, and composition can lead to higher overall productivity …
Energy flows in static and programmable catalysts
OA Abdelrahman, PJ Dauenhauer - ACS Energy Letters, 2023 - ACS Publications
Programmable catalysts that change on the time scale of a catalytic cycle provide a new
opportunity to control the flow of energy to reactants and products to promote faster and …
opportunity to control the flow of energy to reactants and products to promote faster and …
Catalytic resonance theory: the catalytic mechanics of programmable ratchets
Catalytic reaction networks of multiple elementary steps operating under dynamic conditions
via a programmed input oscillation are difficult to interpret and optimize due to reaction …
via a programmed input oscillation are difficult to interpret and optimize due to reaction …
Dynamic Promotion of the Oxygen Evolution Reaction via Programmable Metal Oxides
Hydrogen gas is a promising renewable energy storage medium when produced via water
electrolysis, but this process is limited by the sluggish kinetics of the anodic oxygen …
electrolysis, but this process is limited by the sluggish kinetics of the anodic oxygen …