The progress and outlook of metal single-atom-site catalysis

X Liang, N Fu, S Yao, Z Li, Y Li - Journal of the American Chemical …, 2022 - ACS Publications
Single-atom-site catalysts (SASCs) featuring maximized atom utilization and isolated active
sites have progressed tremendously in recent years as a highly prosperous branch of …

Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Subnanometric Ru clusters with upshifted D band center improve performance for alkaline hydrogen evolution reaction

Q Hu, K Gao, X Wang, H Zheng, J Cao, L Mi… - Nature …, 2022 - nature.com
Subnanometric metal clusters usually have unique electronic structures and may display
electrocatalytic performance distinctive from single atoms (SAs) and larger nanoparticles …

Long‐range interactions in diatomic catalysts boosting electrocatalysis

WH Li, J Yang, D Wang - Angewandte Chemie, 2022 - Wiley Online Library
The simultaneous presence of two active metal centres in diatomic catalysts (DACs) leads to
the occurrence of specific interactions between active sites. Such interactions, referred to as …

Microenvironment engineering of single/dual‐atom catalysts for electrocatalytic application

Y Gao, B Liu, D Wang - Advanced Materials, 2023 - Wiley Online Library
Single/dual‐metal atoms supported on carbon matrix can be modulated by coordination
structure and neighboring active sites. Precisely designing the geometric and electronic …

Emerging low-nuclearity supported metal catalysts with atomic level precision for efficient heterogeneous catalysis

X Zheng, B Li, Q Wang, D Wang, Y Li - Nano research, 2022 - Springer
Supported atomically dispersed metal catalysts (ADMCs) have received enormous attention
due to their high atom utilization efficiency, mass activity and excellent selectivity. Single …

Ru–Co pair sites catalyst boosts the energetics for the oxygen evolution reaction

X Zheng, J Yang, Z Xu, Q Wang, J Wu… - Angewandte Chemie …, 2022 - Wiley Online Library
Manipulating the coordination environment of the active center via anion modulation to
reveal tailored activity and selectivity has been widely achieved, especially for carbon …

Metal-metal interactions in correlated single-atom catalysts

J Shan, C Ye, Y Jiang, M Jaroniec, Y Zheng… - Science …, 2022 - science.org
Single-atom catalysts (SACs) include a promising family of electrocatalysts with unique
geometric structures. Beyond conventional ones with fully isolated metal sites, an emerging …

Superiority of dual‐atom catalysts in electrocatalysis: one step further than single‐atom catalysts

R Li, D Wang - Advanced Energy Materials, 2022 - Wiley Online Library
In recent years, dual‐atom catalysts (DACs) have attracted extensive attention, as an
extension of single‐atom catalysts (SACs). Compared with SACs, DACs have higher metal …

Pinpointing the axial ligand effect on platinum single-atom-catalyst towards efficient alkaline hydrogen evolution reaction

T Zhang, J Jin, J Chen, Y Fang, X Han, J Chen… - Nature …, 2022 - nature.com
Developing active single-atom-catalyst (SAC) for alkaline hydrogen evolution reaction
(HER) is a promising solution to lower the green hydrogen cost. However, the correlations …