The progress and outlook of metal single-atom-site catalysis
X Liang, N Fu, S Yao, Z Li, Y Li - Journal of the American Chemical …, 2022 - ACS Publications
Single-atom-site catalysts (SASCs) featuring maximized atom utilization and isolated active
sites have progressed tremendously in recent years as a highly prosperous branch of …
sites have progressed tremendously in recent years as a highly prosperous branch of …
Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …
achieving a fundamental understanding on the nature of the active sites in bimetallic …
Subnanometric Ru clusters with upshifted D band center improve performance for alkaline hydrogen evolution reaction
Q Hu, K Gao, X Wang, H Zheng, J Cao, L Mi… - Nature …, 2022 - nature.com
Subnanometric metal clusters usually have unique electronic structures and may display
electrocatalytic performance distinctive from single atoms (SAs) and larger nanoparticles …
electrocatalytic performance distinctive from single atoms (SAs) and larger nanoparticles …
Long‐range interactions in diatomic catalysts boosting electrocatalysis
The simultaneous presence of two active metal centres in diatomic catalysts (DACs) leads to
the occurrence of specific interactions between active sites. Such interactions, referred to as …
the occurrence of specific interactions between active sites. Such interactions, referred to as …
Microenvironment engineering of single/dual‐atom catalysts for electrocatalytic application
Y Gao, B Liu, D Wang - Advanced Materials, 2023 - Wiley Online Library
Single/dual‐metal atoms supported on carbon matrix can be modulated by coordination
structure and neighboring active sites. Precisely designing the geometric and electronic …
structure and neighboring active sites. Precisely designing the geometric and electronic …
Emerging low-nuclearity supported metal catalysts with atomic level precision for efficient heterogeneous catalysis
X Zheng, B Li, Q Wang, D Wang, Y Li - Nano research, 2022 - Springer
Supported atomically dispersed metal catalysts (ADMCs) have received enormous attention
due to their high atom utilization efficiency, mass activity and excellent selectivity. Single …
due to their high atom utilization efficiency, mass activity and excellent selectivity. Single …
Ru–Co pair sites catalyst boosts the energetics for the oxygen evolution reaction
Manipulating the coordination environment of the active center via anion modulation to
reveal tailored activity and selectivity has been widely achieved, especially for carbon …
reveal tailored activity and selectivity has been widely achieved, especially for carbon …
Metal-metal interactions in correlated single-atom catalysts
Single-atom catalysts (SACs) include a promising family of electrocatalysts with unique
geometric structures. Beyond conventional ones with fully isolated metal sites, an emerging …
geometric structures. Beyond conventional ones with fully isolated metal sites, an emerging …
Superiority of dual‐atom catalysts in electrocatalysis: one step further than single‐atom catalysts
R Li, D Wang - Advanced Energy Materials, 2022 - Wiley Online Library
In recent years, dual‐atom catalysts (DACs) have attracted extensive attention, as an
extension of single‐atom catalysts (SACs). Compared with SACs, DACs have higher metal …
extension of single‐atom catalysts (SACs). Compared with SACs, DACs have higher metal …
Pinpointing the axial ligand effect on platinum single-atom-catalyst towards efficient alkaline hydrogen evolution reaction
Developing active single-atom-catalyst (SAC) for alkaline hydrogen evolution reaction
(HER) is a promising solution to lower the green hydrogen cost. However, the correlations …
(HER) is a promising solution to lower the green hydrogen cost. However, the correlations …