Molecular oxygen-mediated oxygenation reactions involving radicals

C Tang, X Qiu, Z Cheng, N Jiao - Chemical Society Reviews, 2021 - pubs.rsc.org
Molecular oxygen as a green, non-toxic and inexpensive oxidant has displayed lots of
advantages compared with other oxidants towards more selective, sustainable, and …

Advances in silylation and borylation of fluoroarenes and gem-difluoroalkenes via C–F bond cleavage

J Zhang, S Geng, Z Feng - Chemical Communications, 2021 - pubs.rsc.org
Organoboron and organosilane compounds are widely used in organic synthesis and
pharmaceuticals. In addition, the C–F bond functionalization is a useful tool for the …

Selective Degradation of Styrene‐Related Plastics Catalyzed by Iron under Visible Light

M Wang, J Wen, Y Huang, P Hu - ChemSusChem, 2021 - Wiley Online Library
Efficient degradation of plastics, the vital challenge for a sustainable future, stands in need of
better chemical recycling procedures that help produce commercially valuable small …

Blending aryl ketone in covalent organic frameworks to promote photoinduced electron transfer

M Liu, J Liu, J Li, Z Zhao, K Zhou, Y Li… - Journal of the …, 2023 - ACS Publications
Aryl-ketone derivatives have been acknowledged as promising organic photocatalysts for
photosynthesis. However, they are limited by their photostability and have been less …

Enzyme-Inspired Coordination Polymers for Selective Oxidization of C(sp3)–H Bonds via Multiphoton Excitation

H Huang, X Jing, J Deng, C Meng… - Journal of the American …, 2023 - ACS Publications
Nature's blueprint provides the fundamental principles for expanding the use of abundant
metals in catalysis; however, mimicking both the structure and function of copper enzymes …

Experimental and Computational Studies of the Iron‐Catalyzed Selective and Controllable Defluorosilylation of Unactivated Aliphatic gem‐Difluoroalkenes

H Zhang, E Wang, S Geng, Z Liu, Y He… - Angewandte Chemie …, 2021 - Wiley Online Library
The first iron‐catalyzed defluorosilylation of unactivated gem‐difluoroalkenes was
developed, delivering gem‐disilylated alkenes and (E)‐silylated alkenes with excellent …

Green oxidation of isochromans to isochromanones with molecular oxygen catalyzed by a tetranuclear vanadium cluster

H Huang, B Chen, Y Fu, J Sun, Y Bi… - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary Isochromanone is the core structure of many bioactive
compounds. Direct oxidation of isochromans is one of leading methods for the construction …

Catalyst-free aerobic radical cascade reactions of o-vinylphenylisocyanides with thiols to access 2-thio-substituted quinolines

J Wang, H Liu, Y Liu, W Hao, Y Yang, Y Sun… - Organic Chemistry …, 2022 - pubs.rsc.org
We herein report an efficient and green aerobic radical cascade reaction of o-
vinylphenylisocyanides with thiols to access a broad range of 2-thio-substituted quinolines …

Iron-catalyzed borylation and silylation of unactivated tertiary, secondary, and primary alkyl chlorides

S Wang, M Sun, H Zhang, J Zhang, Y He… - CCS …, 2021 - chinesechemsoc.org
Herein, we describe an iron-catalyzed borylation and silylation of unactivated alkyl
chlorides, delivering the tertiary, secondary, and primary alkylboronic esters, and secondary …

Iron-catalyzed borylation of aryl ethers via cleavage of C–O bonds

X Zeng, Y Zhang, Z Liu, S Geng, Y He, Z Feng - Organic letters, 2020 - ACS Publications
Herein, we report the iron-catalyzed borylation of aryl ethers and aryl amines via cleavage of
C–O and C–N bonds. This protocol does not require the use of Grignard reagents and …