Renewable energy integration with hot compressed water in heavy oil upgrading: A practice toward sustainability

M Hosseinpour, M Soltani, J Nathwani - Journal of Cleaner Production, 2022 - Elsevier
All economies need energy for growth, particularly emerging ones with continued demand
for fossil fuels that move them to unconventional energy sources such as heavy oil …

Upgrading and desulfurization of heavy oils by supercritical water

MT Timko, AF Ghoniem, WH Green - The Journal of Supercritical Fluids, 2015 - Elsevier
Supercritical water upgrading (SCWU) of heavy oils reduces sulfur content and decreases
average molecular weight, without rejecting carbon as coke products. Despite many years of …

Supercritical water desulfurization of organic sulfides is consistent with free-radical kinetics

PR Patwardhan, MT Timko, CA Class, RE Bonomi… - Energy & …, 2013 - ACS Publications
Supercritical water desulfurization (SCWDS) has potential as a technique for removing sulfur
from feedstocks such as heavy oil and bitumen. However, a fundamental understanding of …

Deuterium tracing study of unsaturated aliphatics hydrogenation by supercritical water in upgrading heavy oil. Part II: Hydrogen donating capacity of water in the …

M Hosseinpour, S Fatemi, SJ Ahmadi - The Journal of Supercritical Fluids, 2016 - Elsevier
This paper is the second part of the vacuum residue (VR) cracking in supercritical water and
tracking the chemical behavior of water as the hydrogen donor, using supercritical …

Lumped reaction kinetic models for pyrolysis of heavy oil in the presence of supercritical water

QK Liu, DQ Zhu, XC Tan, PQ Yuan, ZM Cheng… - AIChE …, 2016 - Wiley Online Library
The reaction kinetics of the pyrolysis of heavy oil in the presence of supercritical water
(SCW) and high pressure N2 were measured. At any reaction temperature applied, the …

Application of supercritical water conditions to improve the flowback of fracturing fluid in ultra-low-permeability sandstone formations

Y Li, X Cui, H Li, S Chen, M Chen - Experimental Thermal and Fluid …, 2021 - Elsevier
Hydraulic fracturing is an important approach for stimulating the production of ultra-low-
permeability oil reservoirs; however, the low flowback efficiency of the fracturing fluid (FF) …

Hot Compressed Water for Conversion and Upgrading of Unconventional Oil Resources: State of the Art, Perspectives, and Future Directions

M Hosseinpour, M Fakhroleslam, R Djimasbe… - Energy & …, 2024 - ACS Publications
Unconventional oil resources (oil shale, oil sands, extra heavy oil, and natural bitumen) and
residues (atmospheric and vacuum residua) can exploit hot compressed water (HCW: T> …

Detailed kinetic model for hexyl sulfide pyrolysis and its desulfurization by supercritical water

CA Class, AGK Vasiliou, Y Kida, MT Timko… - Physical Chemistry …, 2019 - pubs.rsc.org
A detailed reaction network is proposed for the pyrolysis and desulfurization of hexyl sulfide
in the presence or absence of both supercritical water (SCW) and hexadecane, but without …

Simulation of supercritical water–hydrocarbon mixing in a cylindrical tee at intermediate Reynolds number: Formulation, numerical method and laminar mixing

A Raghavan, AF Ghoniem - The Journal of Supercritical Fluids, 2014 - Elsevier
The objective of this work is to study the flow dynamics and mixing of supercritical water and
a model hydrocarbon (n-decane), under fully miscible conditions, in a small scale cylindrical …

A sharp interface method for coupling multiphase flow, heat transfer and multicomponent mass transfer with interphase diffusion

P He, AF Ghoniem - Journal of Computational Physics, 2017 - Elsevier
Mixing of partially miscible fluids plays an important role in many physical and chemical
processes. The modeling complexities lie in the tight coupling of the multiphase flow, heat …