Recent advances on the structure–properties relationship of multiblock copolymers

GP Baeza - Journal of Polymer Science, 2021 - Wiley Online Library
Multiblock copolymers represent a fascinating class of materials that sits at the very heart of
industrial applications and fundamental polymer science. They are most often made of a …

3D-MID technology for surface modification of polymer-based composites: a comprehensive review

J Tengsuthiwat, MR Sanjay, S Siengchin, CI Pruncu - Polymers, 2020 - mdpi.com
The three-dimensional molded interconnected device (3D-MID) has received considerable
attention because of the growing demand for greater functionality and miniaturization of …

Kinetic trapping of 3D-printable cyclodextrin-based poly (pseudo) rotaxane networks

Q Lin, L Li, M Tang, S Uenuma, J Samanta, S Li… - Chem, 2021 - cell.com
Synthetically trapping kinetically varied (super) structures of molecular assemblies and
amplifying them to the macroscale is a promising, yet challenging, approach for the …

The Role of the Interface of PLA with Thermoplastic Starch in the Nonisothermal Crystallization Behavior of PLA in PLA/Thermoplastic Starch/SiO2 Composites

D Li, C Luo, J Zhou, L Dong, Y Chen, G Liu, S Qiao - Polymers, 2023 - mdpi.com
Corn starch was plasticized by glycerol suspension in a twin-screw extruder, in which the
glycerol suspension was the pre-dispersion mixture of glycerol with nano-SiO2. Polylactide …

Controllable cell structures of poly (ether-block-amide) foams via isothermal melt crystallization-foaming in supercritical CO2

C Wang, M Xu, Y Chen, Z Xu, L Zhao, D Hu - The Journal of Supercritical …, 2023 - Elsevier
A simple isothermal melt crystallization-foaming method was proposed to regulate the
crystallinity (X c) of PEBA to prepare poly (ether-block-amide)(PEBA) foams with uniform or …

Linear, Star, Comb, and Ring Crystallizable Multiblock Copolymers Investigated by Molecular Dynamics Simulations

J Morthomas, V Viola, V Vallejo-Otero… - Macromolecules, 2023 - ACS Publications
We use coarse-grained molecular dynamics simulations to study the impact of the chain
topology on the structure and thermal and mechanical properties of crystallizable multiblock …

Molecular weight effects on the stress-relaxation behavior of soft thermoplastic elastomer by means of temperature scanning stress relaxation (TSSR)

S Sbrescia, T Engels, E Van Ruymbeke, M Seitz - Journal of Rheology, 2022 - pubs.aip.org
The mechanical properties of multiblock copolymer thermoplastic elastomers (TPEs) are
governed by the interplay of different reversible dynamics [eg, hard block (HB) association …

Reversible–irreversible transition of strain-induced crystallization in segmented copolymers: the critical strain and chain conformation

P Zhu, C Zhou, Y Wang, B Sauer, W Hu… - ACS Applied Polymer …, 2021 - ACS Publications
The formation, growth, and melting of the strain-induced crystallization (SIC) structures of
poly (tetramethylene oxide)(PTMO) were studied during the step-cycle deformation of poly …

Mechanistic Understanding of Sticker Aggregation in Supramolecular Polymers: Quantitative Insights from the Plateau Modulus of Triblock Copolymers

M Nébouy, J Morthomas, C Fusco, L Chazeau… - …, 2022 - ACS Publications
Quantifying the impact of associative group aggregation on the mechanical properties of
dense supramolecular networks remains a challenging problem. To address this question …

Morphological origins of temperature and rate dependent mechanical properties of model soft thermoplastic elastomers

S Sbrescia, J Ju, T Engels… - Journal of Polymer …, 2021 - Wiley Online Library
Thermoplastic elastomers (TPEs) combine high elasticity with melt processability due to their
structural features being based on physical associations rather than chemical crosslinking …