Introduction of fluorine and fluorine‐containing functional groups

T Liang, CN Neumann, T Ritter - … Chemie International Edition, 2013 - Wiley Online Library
Over the past decade, the most significant, conceptual advances in the field of fluorination
were enabled most prominently by organo‐and transition‐metal catalysis. The most …

Einführung von Fluor und fluorhaltigen funktionellen Gruppen

T Liang, CN Neumann, T Ritter - Angewandte Chemie, 2013 - Wiley Online Library
Die wichtigsten konzeptionellen Fortschritt auf dem Gebiet der Fluorierungen der letzten
zehn Jahre wurden durch die Organo‐und Übergangsmetallkatalyse ermöglicht. Die …

Transition metal catalysis and nucleophilic fluorination

C Hollingworth, V Gouverneur - Chemical Communications, 2012 - pubs.rsc.org
Transition metal catalyzed transformations using fluorinating reagents have been developed
extensively for the preparation of synthetically valuable fluorinated targets. This is a topic of …

The chemistry of propargylic and allylic fluorides

MC Pacheco, S Purser, V Gouverneur - Chemical reviews, 2008 - ACS Publications
The presence of fluorine is very often highly advantageous in pharmaceutical and
agrochemical compounds as well as in performance materials. In response to a growing …

Iridium-catalyzed enantioselective fluorination of racemic, secondary allylic trichloroacetimidates

Q Zhang, DP Stockdale, JC Mixdorf… - Journal of the …, 2015 - ACS Publications
The Ir-catalyzed enantioselective fluorination of racemic, branched allylic
trichloroacetimidates with Et3N· 3HF is a mild and efficient route for selective incorporation …

Regio-and enantioselective synthesis of allylic fluorides by electrophilic fluorodesilylation of allyl silanes.

B Greedy, J Paris, T Vidal, V Gouverneur - … Chemie (International ed. in …, 2003 - ora.ox.ac.uk
Enantiopure N-fluorocinchona alkaloids promoted the electrophilic fluorodesilylation of allyl
silanes in a conceptually new approach to the regio-and enantioselective formation of allylic …

Sequential cross-metathesis/electrophilic fluorodesilylation: A novel entry to functionalized allylic fluorides

S Thibaudeau, V Gouverneur - Organic letters, 2003 - ACS Publications
Sequential Cross-Metathesis/Electrophilic Fluorodesilylation: A Novel Entry to Functionalized
Allylic Fluorides | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In …

Conversion of carbon–fluorine bonds α to transition metal centers to carbon–hydrogen, carbon–carbon, and carbon–heteroatom bonds

RP Hughes - European Journal of Inorganic Chemistry, 2009 - Wiley Online Library
Pseudo‐tetrahedral primary fluoroalkyl complexes of iridium provide a template on which to
study the stereoselectivity of carbon–fluorine bond activation α to iridium by external protic …

Synthesis of monofluorinated analogues of lysophosphatidic acid

Y Xu, L Qian, GD Prestwich - The Journal of organic chemistry, 2003 - ACS Publications
Lysophosphatidic acid (LPA, 1-or 2-acyl-sn-glycerol 3-phosphate) displays an intriguing cell
biology that is mediated via interactions both with G-protein coupled seven transmembrane …

Asymmetric fluorination of cyclic tetrasubstituted alkenes with a pendant amide groups under dianionic phase-transfer catalysis

T Niwa, K Ujiie, H Sato, H Egami… - Chemical and …, 2018 - jstage.jst.go.jp
Asymmetric fluorination of cyclic tetrasubstituted alkenes with a pendant amide group was
investigated under dianionic phase-transfer catalysis. Fluorination proceeded with high face …