Chemical routes for the transformation of biomass into chemicals
A Corma, S Iborra, A Velty - Chemical reviews, 2007 - ACS Publications
Vegetable biomass is generated from CO2 and H2O using sunlight as the energy source,
producing O2 as a subproduct. The primary products formed are C6-and C5-sugars that …
producing O2 as a subproduct. The primary products formed are C6-and C5-sugars that …
Heterogeneous catalysts for the one-pot synthesis of chemicals and fine chemicals
MJ Climent, A Corma, S Iborra - Chemical Reviews, 2011 - ACS Publications
The search for alternative cleaner, safer, and environmentally friendly technologies is one of
the priorities in chemistry. With this objective, the reduction of wastes together with the use of …
the priorities in chemistry. With this objective, the reduction of wastes together with the use of …
Probing the Lewis Acidity and Catalytic Activity of the Metal–Organic Framework [Cu3(btc)2] (BTC=Benzene‐1,3,5‐tricarboxylate)
L Alaerts, E Séguin, H Poelman… - … A European Journal, 2006 - Wiley Online Library
An optimized procedure was designed for the preparation of the microporous metal–organic
framework (MOF)[Cu3 (btc) 2](BTC= benzene‐1, 3, 5‐tricarboxylate). The crystalline material …
framework (MOF)[Cu3 (btc) 2](BTC= benzene‐1, 3, 5‐tricarboxylate). The crystalline material …
Sustainable heterogeneous acid catalysis by heteropoly acids
I Kozhevnikov - Handbook of Green Chemistry: Online, 2010 - Wiley Online Library
Heterogeneous acid catalysis by heteropoly acids (HPAs) has the potential for substantial
economic and green benefits. The aim of this chapter is to discuss the perspectives of acid …
economic and green benefits. The aim of this chapter is to discuss the perspectives of acid …
Heterogeneous acid catalysis by heteropoly acids: Approaches to catalyst deactivation
IV Kozhevnikov - Journal of Molecular Catalysis A: Chemical, 2009 - Elsevier
Heterogeneous acid catalysis by heteropoly acids (HPAs) has the potential of great
economic rewards and green benefits. Its application, however, has been limited to some …
economic rewards and green benefits. Its application, however, has been limited to some …
Citronellal as key compound in organic synthesis
Citronellal (3, 7-dimethyl-6-octenal, 1, Fig. 1) is a monoterpene, predominantly formed by the
secondary metabolism of plants. It is typically isolated as a non-racemic mixture of its R and …
secondary metabolism of plants. It is typically isolated as a non-racemic mixture of its R and …
[HTML][HTML] Continuous synthesis of menthol from citronellal and citral over Ni-beta-zeolite-sepiolite composite catalyst
I Simakova, P Mäki-Arvela, M Martinez-Klimov… - Applied Catalysis A …, 2022 - Elsevier
One-pot continuous synthesis of menthols both from citronellal and citral was investigated
over 5 wt% Ni supported on H-Beta-38-sepiolite composite catalyst at 60–70° C under 10 …
over 5 wt% Ni supported on H-Beta-38-sepiolite composite catalyst at 60–70° C under 10 …
Synthesis and catalysis of di-and tetranuclear metal sandwich-type silicotungstates [(γ-SiW10O36) 2M2 (μ-OH) 2] 10− and [(γ-SiW10O36) 2M4 (μ4-O)(μ-OH) 6] 8−(M …
Y Kikukawa, S Yamaguchi, K Tsuchida… - Journal of the …, 2008 - ACS Publications
The di-and tetranuclear metal sandwich-type silicotungstates of Cs10 [(γ-SiW10O36) 2 {Zr
(H2O)} 2 (μ-OH) 2]· 18H2O (Zr2, monoclinic, C 2/c (No. 15), a= 25.3315 (8) Å, b= 22.6699 (7) …
(H2O)} 2 (μ-OH) 2]· 18H2O (Zr2, monoclinic, C 2/c (No. 15), a= 25.3315 (8) Å, b= 22.6699 (7) …
Synthesis of a dialuminum-substituted silicotungstate and the diastereoselective cyclization of citronellal derivatives
Y Kikukawa, S Yamaguchi, Y Nakagawa… - Journal of the …, 2008 - ACS Publications
A novel dialuminum-substituted silicotungstate TBA3H [γ-SiW10O36 {Al (OH2)} 2 (μ-OH) 2]·
4H2O (1, TBA= tetra-n-butylammonium) was synthesized by the reaction of the potassium …
4H2O (1, TBA= tetra-n-butylammonium) was synthesized by the reaction of the potassium …
Insight in the activity and diastereoselectivity of various Lewis acid catalysts for the citronellal cyclization
M Vandichel, F Vermoortele, S Cottenie, DE De Vos… - Journal of …, 2013 - Elsevier
Abstract Industrial (−)-menthol production generally relies on the hydrogenation of (−)-
isopulegol, which is in turn produced with high selectivity by cyclization of (+)-citronellal. This …
isopulegol, which is in turn produced with high selectivity by cyclization of (+)-citronellal. This …