Organic peroxides in aerosol: key reactive intermediates for multiphase processes in the atmosphere
Organic peroxides (POs) are organic molecules with one or more peroxide (− O–O−)
functional groups. POs are commonly regarded as chemically labile termination products …
functional groups. POs are commonly regarded as chemically labile termination products …
Radical chemistry in oxidation flow reactors for atmospheric chemistry research
Z Peng, JL Jimenez - Chemical Society Reviews, 2020 - pubs.rsc.org
Environmental chambers have been playing a vital role in atmospheric chemistry research
for seven decades. In last decade, oxidation flow reactors (OFR) have emerged as a …
for seven decades. In last decade, oxidation flow reactors (OFR) have emerged as a …
Hydrotrioxide (ROOOH) formation in the atmosphere
Organic hydrotrioxides (ROOOH) are known to be strong oxidants used in organic synthesis.
Previously, it has been speculated that they are formed in the atmosphere through the gas …
Previously, it has been speculated that they are formed in the atmosphere through the gas …
Estimation of rate coefficients and branching ratios for reactions of organic peroxy radicals for use in automated mechanism construction
ME Jenkin, R Valorso, B Aumont… - … Chemistry and Physics, 2019 - acp.copernicus.org
Abstract Organic peroxy radicals (RO 2), formed from the degradation of hydrocarbons and
other volatile organic compounds (VOCs), play a key role in tropospheric oxidation …
other volatile organic compounds (VOCs), play a key role in tropospheric oxidation …
Molecular insights into the formation of Criegee intermediates from β-hydroxyperoxy radicals
L Chen, Y Huang, Y Xue, Z Jia - Atmospheric Environment, 2024 - Elsevier
Organic peroxy radicals (RO 2) and Criegee intermediates (CI, carbonyl oxides) are key
reactive species in atmospheric chemistry, and can proceed various reactions influencing …
reactive species in atmospheric chemistry, and can proceed various reactions influencing …
Ether and ester formation from peroxy radical recombination: a qualitative reaction channel analysis
L Franzon, M Camredon, R Valorso… - Atmospheric …, 2024 - acp.copernicus.org
The least volatile organic compounds participating in atmospheric new-particle formation
are very likely accretion products from self-and cross-reactions of peroxy radicals (RO 2). It …
are very likely accretion products from self-and cross-reactions of peroxy radicals (RO 2). It …
Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber …
LG Jahn, DS Wang, SV Dhulipala… - The Journal of Physical …, 2021 - ACS Publications
Chlorine-initiated oxidation of alkanes has been shown to rapidly form secondary organic
aerosol (SOA) at higher yields than OH–alkane reactions. However, the effects of alkane …
aerosol (SOA) at higher yields than OH–alkane reactions. However, the effects of alkane …
Organic peroxy radical chemistry in oxidation flow reactors and environmental chambers and their atmospheric relevance
Oxidation flow reactors (OFRs) are a promising complement to environmental chambers for
investigating atmospheric oxidation processes and secondary aerosol formation. However …
investigating atmospheric oxidation processes and secondary aerosol formation. However …
The reaction of peroxy radicals with OH radicals
C Fittschen - Chemical Physics Letters, 2019 - Elsevier
The reaction of peroxy radicals, RO 2, with OH radicals has long been ignored to play any
role in atmospheric chemistry. Recent experimental and modeling studies show however …
role in atmospheric chemistry. Recent experimental and modeling studies show however …
Can isoprene oxidation explain high concentrations of atmospheric formic and acetic acid over forests?
Formic and acetic acid concentrations are particularly high over forested areas of the world.
However, the gas-phase mechanisms for producing these acids are poorly understood even …
However, the gas-phase mechanisms for producing these acids are poorly understood even …