Fickian diffusion of radionuclides for engineered containment barriers: Diffusion coefficients, porosities, and complicating issues

CD Shackelford, SM Moore - Engineering Geology, 2013 - Elsevier
A review of the literature was undertaken primarily with the goal of discerning the types of
diffusion coefficients that have been reported with respect to diffusion of radionuclides …

Reactive transport modeling of coupled processes in nanoporous media

C Tournassat, CI Steefel - Reviews in Mineralogy and …, 2019 - pubs.geoscienceworld.org
Nanoporous media consist of homogeneous or heterogeneous porous material in which a
significant part of the pore size distribution lies in the nanometer range. Clayey rocks …

The ISSMGE Kerry Rowe Lecture: The role of diffusion in environmental geotechnics

CD Shackelford - Canadian Geotechnical Journal, 2014 - cdnsciencepub.com
Diffusion of contaminants can play a significant if not dominant role in many applications
encountered within the field of environmental geotechnics. The objective of this paper is to …

Limiting membrane and diffusion behavior of a geosynthetic clay liner

CD Shackelford, A Meier, K Sample-Lord - Geotextiles and …, 2016 - Elsevier
Bentonite based geosynthetic clay liners (GCLs) are commonly used as chemical
containment barriers to minimize liquid flow and contaminant transport. The preference for …

Coupled chemical-hydraulic-mechanical behaviour of bentonites

A Dominijanni, M Manassero… - Bio-and Chemo …, 2014 - icevirtuallibrary.com
Bentonites are clay soils characterised by a high specific surface and a permanent negative
electric charge on their solid skeleton. Their common use as hydraulic and contaminant …

Impact of cation–ligand interactions on the permselectivity of ligand-functionalized polymer membranes in single and mixed salt systems

HS Sachar, ES Zofchak, N Marioni, Z Zhang… - …, 2022 - ACS Publications
We conduct molecular dynamics simulations to study the effects of cation–ligand interactions
on salt permeation in ligand-functionalized polymer membranes. Our results indicate that …

[HTML][HTML] Pore-scale mechanisms underlying the behavior of enhanced bentonites exposed to aggressive inorganic solutions

N Guarena, A Dominijanni, M Manassero - Applied Clay Science, 2024 - Elsevier
Understanding the mechanisms that control the hydraulic and semipermeable membrane
behavior of enhanced bentonites (EBs), which comprise natural montmorillonite amended …

A review of the migration of radioactive elements in clay minerals in the context of nuclear waste storage

C Wang, VF Myshkin, VA Khan… - Journal of Radioanalytical …, 2022 - Springer
Clay is a widespread natural mineral. The review considers physical and chemical
properties of clay minerals which are important in terms of geological high-level radioactive …

Processes that control mineral and element abundances in shales

JD Rimstidt, JA Chermak, ME Schreiber - Earth-Science Reviews, 2017 - Elsevier
A shale's composition can be used to infer physical, chemical, and biological processes that
have acted on it over its life history and this knowledge is used to surmise conditions at the …

Laboratory assessment of semi-permeable properties of a natural sodium bentonite

A Dominijanni, N Guarena… - Canadian Geotechnical …, 2018 - cdnsciencepub.com
The relevance of the semi-permeable properties of bentonites, which affect both their
transport processes and mechanical behaviour, has been assessed through the …