Organic synthesis using nitroxides
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
Molecular oxygen-mediated oxygenation reactions involving radicals
Molecular oxygen as a green, non-toxic and inexpensive oxidant has displayed lots of
advantages compared with other oxidants towards more selective, sustainable, and …
advantages compared with other oxidants towards more selective, sustainable, and …
Emerging Trends in Copper-Promoted Radical-Involved C–O Bond Formations
PZ Wang, JR Chen, WJ Xiao - Journal of the American Chemical …, 2023 - ACS Publications
The C–O bond is ubiquitous in biologically active molecules, pharmaceutical agents, and
functional materials, thereby making it an important functional group. Consequently, the …
functional materials, thereby making it an important functional group. Consequently, the …
Visible-light initiated aerobic oxidations: a critical review
The development of new and highly efficient strategies for the rapid construction of
complicated molecular structures has huge implications and remains a preeminent goal in …
complicated molecular structures has huge implications and remains a preeminent goal in …
Conjugated nitroxides
EV Tretyakov, VI Ovcharenko… - Russian Chemical …, 2022 - iopscience.iop.org
In recent years, research dealing with organic paramagnetic compounds such as stable
radicals and high-spin systems has been focused on applied aspects. Several key trends …
radicals and high-spin systems has been focused on applied aspects. Several key trends …
Alkoxyl Radicals Generated under Photoredox Catalysis: A Strategy for anti‐Markovnikov Alkoxylation Reactions
AL Barthelemy, B Tuccio, E Magnier… - Angewandte Chemie …, 2018 - Wiley Online Library
Reported herein is a novel photoredox‐catalyzed approach for ether synthesis and it
involves alkoxyl radicals generated from N‐alkoxypyridinium salts. A wide range of alkenes …
involves alkoxyl radicals generated from N‐alkoxypyridinium salts. A wide range of alkenes …
Radical-mediated difunctionalization of styrenes
X Bao, J Li, W Jiang, C Huo - Synthesis, 2019 - thieme-connect.com
Styrene, an extremely important compound in the chemical industry, is mainly produced by
the dehydrogenation or oxidative dehydrogenation of ethylbenzene. Transformation of this …
the dehydrogenation or oxidative dehydrogenation of ethylbenzene. Transformation of this …
Photoinduced Silylation of N-Heteroarenes and Unsaturated Benzamides with Naphthalimide-Based Organic Photocatalysts
W Zhang, Q Lu, M Wang, Y Zhang, XF Xia… - Organic Letters, 2022 - ACS Publications
Described herein is the development of a general strategy for the silylation of N-
heteroaromatics and unsaturated benzamides via the rational designing of an efficient …
heteroaromatics and unsaturated benzamides via the rational designing of an efficient …
Copper (II)-catalyzed oxidative cross-coupling of anilines, primary alkyl amines, and sodium azide using TBHP: A route to 2-substituted benzimidazoles
D Mahesh, P Sadhu… - The Journal of organic …, 2016 - ACS Publications
Copper (II)-catalyzed oxidative cross-coupling of anilines, primary alkyl amines, and sodium
azide is described in the presence of TBHP at moderate temperature. This one-pot …
azide is described in the presence of TBHP at moderate temperature. This one-pot …
Copper-Catalyzed Silylperoxidation Reaction of α, β-Unsaturated Ketones, Esters, Amides, and Conjugated Enynes
A synthetic method of copper-catalyzed silylperoxidation of α, β-unsaturated carbonyl
compounds and conjugated enynes has been developed. The realization of …
compounds and conjugated enynes has been developed. The realization of …