Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …

Sulfinates are important lynchpin intermediates in pharmaceutical production; however, their
synthesis via photoredox catalysis is challenging because of their facile oxidation. We …

This review highlights the preparation of sodium sulfinates (RSO2Na) and their multifaceted
synthetic applications. Substantial progress has been made over the last decade in the …

Conventionally, sulfones are prepared by oxidation of sulfides with strong oxidants. Now, a
multicomponent reductive cross‐coupling involving an inorganic salt (sodium metabisulfite) …

Here we report the direct conversion of strong, aliphatic C (sp 3)–H bonds into the
corresponding alkyl sulfinic acids via decatungstate photocatalysis. This transformation has …

Developing efficient and selective strategies to approach complex architectures containing
(multi) stereogenic centers has been a long-standing synthetic challenge in both academia …

A catalyst‐free approach for the generation of sulfonyl radicals from aryldiazonium
tetrafluoroborates in the presence of DABCO⋅(SO2) 2 is realized. The combination of …

Sulfonyl compounds have attracted considerable interest due to their extensive applications
in drug discovery. Access to the assembly of SO2-containing compounds via the …

The potential of merging photoredox and nickel catalysis to perform multicomponent alkene
difunctionalizations under visible‐light irradiation is demonstrated here. Secondary and …