Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …

The combination of the copper (I)–iodide entity with organic ligands gives rise to a large
variety of CuII polynuclear structures in the form of molecular complexes or extended …

Natural antioxidants, including polyphenols, flavonoids, anthocyanins and carotenoids, play
an important role in the treatment and prevention of a large number of diseases. However …

N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …

Redox-active ligands in catalysis - Chemical Society Reviews (RSC Publishing) DOI:10.1039/C2CS35228A
Royal Society of Chemistry View PDF VersionPrevious ArticleNext Article DOI: 10.1039/C2CS35228A …

This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …

We have recently reported on several Fe catalysts for N2-to-NH3 conversion that operate at
low temperature (− 78° C) and atmospheric pressure while relying on a very strong …

Our currently limited understanding of the mechanism of biological dinitrogen fixation [1]–ie
the reduction of N2 to two equivalents of ammonia by addition of protons and electrons …

The biological reduction of N2 to give NH3 may occur by one of two predominant pathways
in which nitrogenous N x H y intermediates, including hydrazine (N2H4), diazene (N2H2) …

A three-coordinate cobalt (I) complex exhibits high catalytic efficiency and selectivity as well
as good functional group compatibility in alkyne hydrosilylation.[Co (IAd)(PPh3)(CH2TMS)] …