Dispersity effects in polymer self-assemblies: a matter of hierarchical control

KEB Doncom, LD Blackman, DB Wright… - Chemical Society …, 2017 - pubs.rsc.org
Advanced applications of polymeric self-assembled structures require a stringent degree of
control over such aspects as functionality location, morphology and size of the resulting …

Development of macromolecules and supramolecules based on silicon and arsenic chemistries

H Imoto - Polymer Journal, 2018 - nature.com
Organic–inorganic hybrids are one of the most important tools in materials science. Since
the incorporation of abundant elements into single molecules realizes molecular-level …

Alkenyl-Functionalized Open-Cage Silsesquioxanes (RSiMe2O)3R′7Si7O9: A Novel Class of Building Nanoblocks

K Stefanowska, J Szyling, J Walkowiak… - Inorganic …, 2021 - ACS Publications
Trifunctional incompletely condensed polyhedral oligomeric silsesquioxanes (RSiMe2O)
3R′ 7Si7O9 (IC-POSS s) are considered as intriguing building nanoblocks dedicated to …

One-pot strategy for synthesis of open-cage silsesquioxane monomers

R Katoh, H Imoto, K Naka - Polymer Chemistry, 2019 - pubs.rsc.org
Element blocks, which are polymerizable functional units composed of diverse elements,
have increasingly attracted attention to construct advanced organic–inorganic hybrid …

Corner‐and Side‐Opened Cage Silsesquioxanes: Structural Effects on the Materials Properties

H Imoto, Y Ueda, Y Sato, M Nakamura… - European Journal of …, 2020 - Wiley Online Library
Open‐cage silsesquioxane, in which traditional closed‐cage silsesquioxane is partially
hydrolyzed, is a promising class of building blocks for constructing organic‐inorganic …

Fabrication of composite films with poly (methyl methacrylate) and incompletely condensed cage‐silsesquioxane fillers

S Yuasa, Y Sato, H Imoto, K Naka - Journal of Applied Polymer …, 2018 - Wiley Online Library
Polyhedral oligomeric silsesquioxane (POSS) is a promising nanofiller for tuning properties
of optically transparent polymer materials. On the other hand, traditional completely …

Thiol-ene-mediated degradable POSS-PEG/PEG hybrid hydrogels as potential cell scaffolds in tissue engineering

Y He, T Jiang, C Li, C Zhou, G Yang, J Nie… - Polymer Degradation …, 2023 - Elsevier
Tissue engineering provides therapeutic strategies for the loss or failure of human organs
and tissues. As a three-dimensional biomaterial that simulates extracellular matrix (ECM) in …

Control of intramolecular excimer emission in luminophore-integrated ionic POSSs possessing flexible side-chains

H Narikiyo, M Gon, K Tanaka, Y Chujo - Materials Chemistry Frontiers, 2018 - pubs.rsc.org
Polycyclic aromatic hydrocarbons such as naphthalene, anthracene and pyrene were
integrated onto polyhedral oligomeric silsesquioxanes (POSSs) having flexible ionic linkers …

Hydrolytically degradable POSS-PEG hybrid hydrogels prepared in aqueous phase with tunable mechanical properties, swelling ratio and degradation rate

J Shen, H Li, C Lu, G Yang, F Wang, J Nie, X Hu… - Reactive and Functional …, 2018 - Elsevier
A series of hydrolytically degradable polyhedral oligomeric silsesquioxanes (POSS)-poly
(ethylene glycol)(PEG) hybrid hydrogels were prepared by covalently grafting hydrophobic …

Synthesis of thiol-terminated PEG-functionalized POSS cross-linkers and fabrication of high-strength and hydrolytic degradable hybrid hydrogels in aqueous phase

H Li, J Dai, Q Xu, C Lu, G Yang, F Wang, J Nie… - European Polymer …, 2019 - Elsevier
A series of high-strength and hydrolytic degradable POSS-PEG hybrid hydrogels were
successfully fabricated by Michael addition reaction of 4-arm-PEG-maleimide with thiol …