In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy
J Timoshenko, B Roldan Cuenya - Chemical reviews, 2020 - ACS Publications
During the last decades, X-ray absorption spectroscopy (XAS) has become an
indispensable method for probing the structure and composition of heterogeneous catalysts …
indispensable method for probing the structure and composition of heterogeneous catalysts …
A theory/experience description of support effects in carbon-supported catalysts
The support plays an important role for supported metal catalysts by positioning itself as a
macromolecular ligand, which conditions the nature of the active site and contributes …
macromolecular ligand, which conditions the nature of the active site and contributes …
Dilute alloys based on Au, Ag, or Cu for efficient catalysis: from synthesis to active sites
The development of new catalyst materials for energy-efficient chemical synthesis is critical
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …
Supervised machine-learning-based determination of three-dimensional structure of metallic nanoparticles
Tracking the structure of heterogeneous catalysts under operando conditions remains a
challenge due to the paucity of experimental techniques that can provide atomic-level …
challenge due to the paucity of experimental techniques that can provide atomic-level …
High Zn/Al ratios enhance dehydrogenation vs hydrogen transfer reactions of Zn-ZSM-5 catalytic systems in methanol conversion to aromatics
I Pinilla-Herrero, E Borfecchia, J Holzinger… - Journal of catalysis, 2018 - Elsevier
Two series of Zn-ZSM-5 catalysts were prepared by ion exchanging two commercial zeolites
with different Si/Al ratios (40 and 15) with increasing Zn loadings. The nature of the Zn sites …
with different Si/Al ratios (40 and 15) with increasing Zn loadings. The nature of the Zn sites …
Physicochemical characterization of nanomaterials: Polymorph, composition, wettability, and thermal stability
Many methods have been used for evaluating physicochemical properties of nanomaterials
(NMs). Characterization of nanoparticles (NPs) includes the determination not only of size …
(NMs). Characterization of nanoparticles (NPs) includes the determination not only of size …
“Inverting” X-ray absorption spectra of catalysts by machine learning in search for activity descriptors
J Timoshenko, AI Frenkel - Acs Catalysis, 2019 - ACS Publications
The rapid growth of methods emerging in the past decade for synthesis of “designer”
catalysts—ranging from the size and shape-selected nanoparticles to mass-selected …
catalysts—ranging from the size and shape-selected nanoparticles to mass-selected …
Aqueous phase catalytic and electrocatalytic hydrogenation of phenol and benzaldehyde over platinum group metals
The mechanisms of aqueous-phase thermal catalytic hydrogenation (TCH) and
electrocatalytic hydrogenation (ECH) of organic molecules over Pt group metals are not as …
electrocatalytic hydrogenation (ECH) of organic molecules over Pt group metals are not as …
Adsorbate-induced structural evolution of Pd catalyst for selective hydrogenation of acetylene
This work describes the transformation of Pd species under reaction conditions to control the
reactivity of heterogeneous catalysts, in which the real active sites for hydrogenation differ …
reactivity of heterogeneous catalysts, in which the real active sites for hydrogenation differ …
Tandem site-and size-controlled Pd nanoparticles for the directed hydrogenation of furfural
SM Rogers, CRA Catlow, CE Chan-Thaw… - ACS …, 2017 - ACS Publications
The conversion of biomass to useful chemical products requires precise catalytic properties
to achieve the required activity, selectivity, and durability. Here we show, through optimized …
to achieve the required activity, selectivity, and durability. Here we show, through optimized …