Electrochemical late-stage functionalization
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …
diversification of novel molecular entities with improved physicochemical or biological …
Cooperative coupling of oxidative organic synthesis and hydrogen production over semiconductor-based photocatalysts
MY Qi, M Conte, M Anpo, ZR Tang, YJ Xu - Chemical Reviews, 2021 - ACS Publications
Merging hydrogen (H2) evolution with oxidative organic synthesis in a semiconductor-
mediated photoredox reaction is extremely attractive because the clean H2 fuel and high …
mediated photoredox reaction is extremely attractive because the clean H2 fuel and high …
Electroreductive Cross‐Electrophile Coupling (eXEC) Reactions
Y Liu, P Li, Y Wang, Y Qiu - Angewandte Chemie, 2023 - Wiley Online Library
Electrochemistry utilizes electrons as a potent, controllable, and traceless alternative to
chemical oxidants or reductants, and typically offers a more sustainable option for achieving …
chemical oxidants or reductants, and typically offers a more sustainable option for achieving …
The Rise of Boron-Containing Compounds: Advancements in Synthesis, Medicinal Chemistry, and Emerging Pharmacology
Boron-containing compounds (BCC) have emerged as important pharmacophores. To date,
five BCC drugs (including boronic acids and boroles) have been approved by the FDA for …
five BCC drugs (including boronic acids and boroles) have been approved by the FDA for …
Cross-Electrophile Coupling: Principles, Methods, and Applications in Synthesis
LE Ehehalt, OM Beleh, IC Priest, JM Mouat… - Chemical …, 2024 - ACS Publications
Cross-electrophile coupling (XEC), defined by us as the cross-coupling of two different σ-
electrophiles that is driven by catalyst reduction, has seen rapid progression in recent years …
electrophiles that is driven by catalyst reduction, has seen rapid progression in recent years …
Boron insertion into alkyl ether bonds via zinc/nickel tandem catalysis
Mild methods to cleave the carbon-oxygen (C− O) bond in alkyl ethers could simplify
chemical syntheses through the elaboration of these robust, readily available precursors …
chemical syntheses through the elaboration of these robust, readily available precursors …
Cu-catalysed enantioselective radical heteroatomic S–O cross-coupling
YF Cheng, ZL Yu, Y Tian, JR Liu, HT Wen, NC Jiang… - Nature Chemistry, 2023 - nature.com
The transition-metal-catalysed cross-coupling reaction has established itself as one of the
most reliable and practical synthetic tools for the efficient construction of carbon …
most reliable and practical synthetic tools for the efficient construction of carbon …
A General Three-Component Alkyl Petasis Boron–Mannich Reaction
Aryl amines are one of the most common moieties in biologically active molecules, and
approximately 37% of drug candidates contain aromatic amines. Recent advancements in …
approximately 37% of drug candidates contain aromatic amines. Recent advancements in …
Mechanistic views and computational studies on transition-metal-catalyzed reductive coupling reactions
A Duan, F Xiao, Y Lan, L Niu - Chemical Society Reviews, 2022 - pubs.rsc.org
Transition-metal-catalyzed reductive coupling reactions have been considered as a
powerful tool to convert two electrophiles into value-added products. Numerous related …
powerful tool to convert two electrophiles into value-added products. Numerous related …
[HTML][HTML] Hydroelementation of diynes
This review highlights the hydroelementation reactions of conjugated and separated diynes,
which depending on the process conditions, catalytic system, as well as the type of reagents …
which depending on the process conditions, catalytic system, as well as the type of reagents …