Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

In 1967 Pederson reported the synthesis of macrocyclic crown ethers and their ability to
selectively bind alkali and alkaline earth ions, 1, 2 and since then supramolecular …

Polynuclear coordination clusters have become of particular interest in recent times as a
result of their relevance to bioinorganic chemistry and to the special area of molecule-based …

This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Complexes of high nuclearity, symmetry, and architectural beauty have long fascinated
chemists, owing both to their aesthetically pleasing nature and to their often interesting …

The reaction between N-methydiethanolamine (mdeaH2), benzoic acid, FeCl3, and DyCl3
yields a decanuclear coordination cluster,[Dy3Fe7 (μ4-O) 2 (μ3-OH) 2 (mdea) 7 (μ …

The combination of diol-type ligands with paramagnetic transition metal ions has led to the
isolation of a host of new homometallic and heterometallic clusters, high-spin molecules and …

Abstract Complexes [Fe9 (X) 2 (O2CMe) 8 {(2‐py) 2CO2} 4](X−= OH−(1), N3−(2), and
NCO−(3)) have been prepared by a route previously employed for the synthesis of …

Herein, the coordination chemistry of a series of Cu (II) complexes of various aminoalcohol
and benzoate ligands was explored. The pH-dependent reactions of copper (II) salts with …

The structures and magnetic properties of a family of new octanuclear heterometallic 3d-4f
complexes [MnIII4LnIII4 (μ3-OH) 4 (μ2, η1-X) 4 (O2CBut) 8 (t-bdea) 4]· solv, where X= N3 …