Formation and Transformation of Clathrate Hydrates under Interstellar Conditions

J Ghosh, G Vishwakarma, R Kumar… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Continuing efforts by many research groups have led to the discovery of∼ 240
species in the interstellar medium (ISM). Observatory-and laboratory-based astrochemical …

Tracking cubic ice at molecular resolution

X Huang, L Wang, K Liu, L Liao, H Sun, J Wang, X Tian… - Nature, 2023 - nature.com
Ice is present everywhere on Earth and has an essential role in several areas, such as cloud
physics, climate change and cryopreservation. The role of ice is determined by its formation …

Induced Migration of CO2 from Hydrate Cages to Amorphous Solid Water under Ultrahigh Vacuum and Cryogenic Conditions

G Vishwakarma, BK Malla, KP Reddy… - The Journal of …, 2023 - ACS Publications
Restricted migration of reactive species limits chemical transformations within interstellar
and cometary ices. We report the migration of CO2 from clathrate hydrate (CH) cages to …

Formation of ethane clathrate hydrate in ultrahigh vacuum by thermal annealing

BK Malla, G Vishwakarma, S Chowdhury… - The Journal of …, 2022 - ACS Publications
The existence of many molecules in the form of clathrate hydrates (CHs) in ultrahigh vacuum
(UHV) and cryogenic conditions has not been explored adequately. In the present study, a …

Existence of Acetaldehyde Clathrate Hydrate and Its Dissociation Leading to Cubic Ice under Ultrahigh Vacuum and Cryogenic Conditions

G Vishwakarma, BK Malla, S Chowdhury… - The Journal of …, 2023 - ACS Publications
Acetaldehyde in a dilute aqueous solution gets hydrated to produce a geminal diol under
atmospheric conditions. The acetaldehyde–water ice system under high pressure also …

Tip-Enhanced Raman Analysis of Plasmonic and Photocatalytic Properties of Copper Nanomaterials

Z Li, D Kurouski - The Journal of Physical Chemistry Letters, 2021 - ACS Publications
Theoretical predictions suggest that, in addition to gold (Au) and silver (Ag), several other
metals such as copper (Cu) and aluminum (Al) can be used as plasmonic materials …

Distortion of the Host Water Cages of Structure I Gas Hydrates: Structural Analysis of C2H4 Hydrate by Powder X-ray Diffraction

S Takeya, A Hachikubo - The Journal of Physical Chemistry C, 2021 - ACS Publications
This study investigated the crystal structure and composition of C2H4 hydrate, prepared from
finely powdered ice and C2H4 gas, using powder X-ray diffraction (PXRD). A …

Growth of Clathrate Hydrates in Nanoscale Ice Films Observed Using Electron Diffraction and Infrared Spectroscopy

BK Malla, DS Yang, T Pradeep - The Journal of Physical …, 2024 - ACS Publications
Clathrate hydrates (CHs) are believed to exist in cold regions of space, such as comets and
icy moons. While spectroscopic studies have explored their formation under similar …

In situ X-ray diffraction study on hydrate formation at low temperature in a high vacuum

RPC Bauer, A Ravichandran, JS Tse… - The Journal of …, 2021 - ACS Publications
The condition for incorporating simple gases with H2O to form clathrate hydrates in
protosolar nebula is a subject of topical interest. Methane and carbon dioxide clathrate …

Facile Crystallization of Ice Ih via Formaldehyde Hydrate in Ultrahigh Vacuum under Cryogenic Conditions

J Ghosh, G Vishwakarma, S Das… - The Journal of Physical …, 2021 - ACS Publications
Although hexagonal ice (ice Ih) is the most common and highly studied crystalline form of
ice, its nucleation from clathrate hydrates is poorly understood. Here, we report the formation …