Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands
C Fliedel, A Ghisolfi, P Braunstein - Chemical reviews, 2016 - ACS Publications
The aim of this review is to highlight how the diversity generated by N-substitution in the well-
known short-bite ligand bis (diphenylphosphino) amine (DPPA) allows a fine-tuning of the …
known short-bite ligand bis (diphenylphosphino) amine (DPPA) allows a fine-tuning of the …
Nickel-catalyzed transfer hydrogenation of ketones using ethanol as a solvent and a hydrogen donor
N Castellanos-Blanco, A Arévalo, JJ García - Dalton Transactions, 2016 - pubs.rsc.org
We report a nickel (0)-catalyzed direct transfer hydrogenation (TH) of a variety of alkyl–aryl,
diaryl, and aliphatic ketones with ethanol. This protocol implies a reaction in which a primary …
diaryl, and aliphatic ketones with ethanol. This protocol implies a reaction in which a primary …
Catalytic applications of small bite-angle diphosphorus ligands with single-atom linkers
SM Mansell - Dalton Transactions, 2017 - pubs.rsc.org
Diphosphorus ligands connected by a single atom (R2PEPR2; E= CR2, CCR2 and NR) give
chelating ligands with very small bite-angles (natural bite-angle of 72° for dppm) as well as …
chelating ligands with very small bite-angles (natural bite-angle of 72° for dppm) as well as …
Electrochemical, mechanistic, and DFT studies of amine derived diphosphines containing Ru (II)–cymene complexes with potent in vitro cytotoxic activity against HeLa …
JP da Silva, O Fuganti, MG Kramer, G Facchin… - Dalton …, 2020 - pubs.rsc.org
Complexes with general formula [RuCl (η6-p-cymene)(P–NR–P)] X (R= CH2Py (Py=
pyridine)–[1a]+, CH2Ph (Ph= phenyl)–[1b]+, Ph–[1c] and p-tol (p-tol= p-tolyl)–[1d]+; X= PF6 …
pyridine)–[1a]+, CH2Ph (Ph= phenyl)–[1b]+, Ph–[1c] and p-tol (p-tol= p-tolyl)–[1d]+; X= PF6 …
Synthesis, spectroscopic and catalytic properties of some new boron hybrid molecule derivatives by BF2 and BPh2 chelation
A new series of Schiff base ligands (L 1–L 3) and their corresponding fluorine/phenyl boron
hybrid complexes [L n BF 2] and [L n BPh 2](n= 1, 2 or 3) have been synthesized and well …
hybrid complexes [L n BF 2] and [L n BPh 2](n= 1, 2 or 3) have been synthesized and well …
Synthesis and catalytic activity of ruthenium (II) complexes containing pyridine-based tridentate triamines (′ NNN⌢⌢′) and pyridine carboxylate ligands (NO⌢)
The reaction of [(p-cymene) RuCl2] 2 with K [NO⌢ ab](NO⌢-= 2-picolinate, a or 2-
quinaldinate, b) gave neutral [(p-cymene) RuCl (NO⌢ ab)](1a–b), complexes which were …
quinaldinate, b) gave neutral [(p-cymene) RuCl (NO⌢ ab)](1a–b), complexes which were …
The first application of C2-symmetric ferrocenyl phosphinite ligands for rhodium-catalyzed asymmetric transfer hydrogenation of various ketones
Homogeneous catalysis has been responsible for many major recent developments in
synthetic organic chemistry. The combined use of organometallic and coordination …
synthetic organic chemistry. The combined use of organometallic and coordination …
Enantioselective transfer hydrogenation of various ketones with novel efficient iridium (III) ferrocenyl-phosphinite catalysts
N Meric, M Aydemir - Journal of Organometallic Chemistry, 2016 - Elsevier
The asymmetric reduction of prochiral ketones is a pivotal reaction for the preparation of
chiral alcohols which form an extremely important class of intermediates for fine chemicals …
chiral alcohols which form an extremely important class of intermediates for fine chemicals …
Bis (diphenylphosphino) amines-containing ruthenium cymene complexes as potential anti-Mycobacterium tuberculosis agents
Several ruthenium complexes have been investigated regarding anti-Mycobacterium
tuberculosis (anti-MTb) activity, with some diphosphine-containing ruthenium complexes …
tuberculosis (anti-MTb) activity, with some diphosphine-containing ruthenium complexes …
Rhodium‐catalyzed transfer hydrogenation with aminophosphines and analysis of electrical characteristics of rhodium (I) complex/n‐Si heterojunctions
A series of novel neutral mononuclear rhodium (I) complexes of the P―NH ligands have
been prepared starting from [Rh (cod) Cl] 2 complex. Structural elucidation of the complexes …
been prepared starting from [Rh (cod) Cl] 2 complex. Structural elucidation of the complexes …