Reactions of hydrosilanes with transition metal complexes

JY Corey - Chemical Reviews, 2016 - ACS Publications
This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …

Activation of the Si–B interelement bond: mechanism, catalysis, and synthesis

M Oestreich, E Hartmann, M Mewald - Chemical Reviews, 2013 - ACS Publications
Interelement compounds, that is, compounds containing an interelement bond, 1 are
attractive main group element precursors as these provide the opportunity to transfer both …

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

K Semba, T Fujihara, J Terao, Y Tsuji - Tetrahedron, 2015 - Elsevier
Organoboronic acids and their derivatives are useful reagents in carbon–carbon and carbon–
heteroatom bond formations. 1 In addition to having reasonable reactivities, organoboronic …

Transition-metal-catalyzed site-selective C–H functionalization of quinolines beyond C2 selectivity

T Iwai, M Sawamura - ACS Catalysis, 2015 - ACS Publications
Quinoline is an important scaffold in many natural products, biologically active compounds,
and functional materials. The C–H functionalization of quinoline scaffolds by transition metal …

Enantioselective C–H bond addition of pyridines to alkenes catalyzed by chiral half-sandwich rare-earth complexes

G Song, WWN O, Z Hou - Journal of the American Chemical …, 2014 - ACS Publications
Cationic half-sandwich scandium alkyl complexes bearing monocyclopentadienyl ligands
embedded in chiral binaphthyl backbones act as excellent catalysts for the enantioselective …

Catalytic Dearomatization of N‐Heteroarenes with Silicon and Boron Compounds

S Park, S Chang - Angewandte Chemie International Edition, 2017 - Wiley Online Library
Dearomatized N‐heterocycles are an important class of structural motifs for organic
synthesis and chemical biology. The catalytic dearomative reduction of unactivated N …

Asymmetric Cu-catalyzed 1, 4-dearomatization of pyridines and pyridazines without preactivation of the heterocycle or nucleophile

MW Gribble Jr, S Guo, SL Buchwald - Journal of the American …, 2018 - ACS Publications
We show that a chiral copper hydride (CuH) complex catalyzes C–C bond-forming
dearomatization of pyridines and pyridazines at room temperature. The catalytic reaction …

Nucleophilic dearomatization of activated pyridines

G Bertuzzi, L Bernardi, M Fochi - Catalysts, 2018 - mdpi.com
Amongst nitrogen heterocycles of different ring sizes and oxidation statuses,
dihydropyridines (DHP) occupy a prominent role due to their synthetic versatility and …

Recent advances in the C–H-functionalization of the distal positions in pyridines and quinolines

DE Stephens, OV Larionov - Tetrahedron, 2015 - Elsevier
C–H-functionalization has emerged as a powerful tool for the synthesis of heterocyclic
compounds. 1 However, with numerous C–H-bonds simultaneously available for activation …

Conversion of Pyridine to Imidazo[1,2-a]pyridines by Copper-Catalyzed Aerobic Dehydrogenative Cyclization with Oxime Esters

H Huang, X Ji, X Tang, M Zhang, X Li, H Jiang - Organic letters, 2013 - ACS Publications
Conversion of Pyridine to Imidazo[1,2-a]pyridines by Copper-Catalyzed Aerobic
Dehydrogenative Cyclization with Oxime Esters | Organic Letters ACS ACS Publications C&EN …