Recent developments in the synthesis and applications of terpyridine-based metal complexes: a systematic review

SF Kainat, MB Hawsawi, EU Mughal, N Naeem… - RSC …, 2024 - pubs.rsc.org
Terpyridine-based metal complexes have emerged as versatile and indispensable building
blocks in the realm of modern chemistry, offering a plethora of applications spanning from …

Metal‐Terpyridine Complexes in Catalytic Application–A Spotlight on the Last Decade

A Winter, US Schubert - ChemCatChem, 2020 - Wiley Online Library
Abstract 2, 2′: 6′, 2′′‐Terpyridine (tpy) and its derivatives represent highly versatile
ligands for the complexation of transition metal ions. Today, such complexes are employed …

Hydrogen transfer reactions of carbonyls, alkynes, and alkenes with noble metals in the presence of alcohols/ethers and amines as hydrogen donors

E Baráth - Catalysts, 2018 - mdpi.com
Hydrogen transfer reactions have exceptional importance, due to their applicability in
numerous synthetic pathways, with academic as well as industrial relevance. The most …

Hydration of Nitriles Catalyzed by Ruthenium Complexes: Role of Dihydrogen Bonding Interactions in Promoting Base-Free Catalysis

S Yadav, R Gupta - Inorganic Chemistry, 2022 - ACS Publications
Ru (II) complexes of amide-phosphine-based tridentate ligands additionally containing
pyridine, isoquinoline, and quinoline rings have been synthesized, and their catalytic utility …

Heteroditopic Ru (II)–and Ir (III)–NHC complexes with pendant 1, 2, 3-triazole/triazolylidene groups: stereoelectronic impact on transfer hydrogenation of unsaturated …

PM Illam, SNR Donthireddy, S Chakrabartty… - Organometallics, 2019 - ACS Publications
Imidazol-2-ylidene (ImNHC) and 1, 2, 3-traizol-5-ylidene (tzNHC) have been established as
important classes of carbene ligands in homogeneous catalysis. To develop Ru (II)/Ir (III) …

Terpyridine diphosphine ruthenium complexes as efficient photocatalysts for the transfer hydrogenation of carbonyl compounds

M Ballico, D Alessi, C Jandl, D Lovison… - … –A European Journal, 2022 - Wiley Online Library
The cationic achiral and chiral terpyridine diphosphine ruthenium complexes [RuCl
(PP)(tpy)] Cl (PP= dppp (1),(R, R)‐Skewphos (2) and (S, S)‐Skewphos (3)) are easily …

Base-Free Transfer Hydrogenation Catalyzed by Ruthenium Hydride Complexes of Coumarin-Amide Ligands

S Yadav, R Gupta - ACS Sustainable Chemistry & Engineering, 2023 - ACS Publications
Two sets of Ru (II) complexes,[Ru–Cl](1–3) and [Ru–H](4–6), supported with coumarin-
amide-based ligands have been synthesized and characterized. In these complexes, the …

Cobalt Complexes as Efficient Cooperative Catalysts for Transfer Hydrogenation

S Yadav, D Prabha, D Ahluwalia… - European Journal of …, 2022 - Wiley Online Library
Cobalt complexes of amide‐based ligands appended with protonated heterocyclic rings are
utilized as the earth‐abundant catalysts for the transfer hydrogenation of assorted carbonyl …

Novel ruthenium complexes bearing bipyridine-based and N-heterocyclic carbene-supported pyridine (NCN) ligands: The influence of ligands on catalytic transfer …

A Piyasaengthong, LJ Williams, DS Yufit… - Dalton …, 2022 - pubs.rsc.org
Transfer hydrogenation (TH) is a powerful synthetic tool in the production of secondary
alcohols from ketones by using a non-H2 hydrogen source along with metal catalysts …

Cyclometalated and NNN Terpyridine Ruthenium Photocatalysts and Their Cytotoxic Activity

M Ballico, D Alessi, E Aneggi, M Busato, D Zuccaccia… - Molecules, 2024 - mdpi.com
The cyclometalated terpyridine complexes [Ru (η2-OAc)(NC-tpy)(PP)](PP= dppb 1,(R, R)-
Skewphos 4,(S, S)-Skewphos 5) are easily obtained from the acetate derivatives [Ru (η2 …