Recent advances in the synthesis and reactivity of MIDA boronates
Organoboron compounds have a wide-range of applications in synthetic methodologies,
natural products, and bioactive molecule synthesis. The sensitivity of boronic acid toward …
natural products, and bioactive molecule synthesis. The sensitivity of boronic acid toward …
Electrophilic Fluorination of Alkenes via Bora‐Wagner–Meerwein Rearrangement. Access to β‐Difluoroalkyl Boronates
The electrophilic fluorination of geminal alkyl substituted vinyl‐Bmida derivatives proceeds
via bora‐Wagner–Meerwein rearrangement. According to DFT modelling studies this …
via bora‐Wagner–Meerwein rearrangement. According to DFT modelling studies this …
Reactivities of α‐Oxo BMIDA Gold Carbenes Generated by Gold‐Catalyzed Oxidation of BMIDA‐Terminated Alkynes
Y Zheng, J Jiang, Y Li, Y Wei, J Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
An oxidative strategy is reported to access α‐oxo BMIDA gold carbenes directly from BMIDA‐
terminated alkynes. Besides offering expedient access to seldom studied boryl metal …
terminated alkynes. Besides offering expedient access to seldom studied boryl metal …
Sigmatropic rearrangements of B (MIDA)-propargylic alcohols towards the diverse synthesis of α-functionalized organoborons
J Qian, LC Liu, ZH Chen, Y Liu, Y Li, Q Li… - Science China …, 2024 - Springer
Abstract α-Functionalized organoborons are useful building blocks and key structural
elements in functional molecules. Their previous synthesis relied on the famous Matteson …
elements in functional molecules. Their previous synthesis relied on the famous Matteson …
Reactivity of 1, 3-enyne MIDA boronates: exploration of novel 1, 2-alkyne shift via gem-difluorination
The discovery of a new class of heteroatom-rich boron-containing molecules (BCMs) and
iterative cross-coupling (ICC) partners created a toolbox for future drug developments using …
iterative cross-coupling (ICC) partners created a toolbox for future drug developments using …
Synthesis and luminescence of monohalogenated B18H22 clusters
KP Anderson, AL Rheingold, PI Djurovich, O Soman… - Polyhedron, 2022 - Elsevier
This work advances the foundation of anti-B 18 H 22 chemistry by exploring cluster reactivity
in the context of monohalogenation and the luminescent properties of the resulting …
in the context of monohalogenation and the luminescent properties of the resulting …