Isocyanides (isonitriles or carbylamine) have been intensively used in organic synthesis to
prepare a diverse variety of N‐heterocycles on the basis of the carbene‐like reactivity of …

Past decades have witnessed significant advance of isocyanides as a class of versatile
organic synthons as well as their broad applications in multi-component reactions (MCRs) …

New radical-triggered three-component bicyclization cascades of 2-alkynyl aryldiazonium
tetrafluoroborates with a sulfur dioxide surrogate DABCO·(SO2) 2 and internal alkynes such …

An efficient TMSOTf-promoted selective triple consecutive insertions of tert-butyl isocyanide
into aldehydes has been developed, affording pharmacological interesting 4-cyanooxazoles …

In this work, an unprecedented route is described for the synthesis of 2-amino-4-
cyanopyrrole derivatives via palladium-catalyzed reductive isocyanide insertion of alkynyl …

In the presence of a catalytic amount of Pd (OAc) 2 and a stoichiometric amount of tert-
butylamine, the reaction of propargyl carbonates, isocyanides, and alcohols afforded …

Iron-Catalyzed Aerobic Oxidation and Annulation Reaction of Pyridine and α-Substituted Allenoate
toward Functionalized Indolizine | Organic Letters ACS ACS Publications C&EN CAS Find my …

A palladium-catalyzed tandem reaction of N-(2-iodophenyl)-4-methyl-N-(propa-1, 2-dien-1-
yl) benzenesulfonamide with isocyanide is described to divergently produce aza …

A palladium-catalyzed multicomponent reaction (MCR) of propargylic carbonates with
isocyanides is reported. Remarkably, the orderly insertion of isocyanides affords two types of …

A new and highly eco-friendly approach to diverse and functionalized oxazolo [5, 4-b]
indoles with good yield and high diastereoselectivity (up to> 99: 1) has been disclosed from …