In this Perspective we present a comprehensive study of the multiple reaction products of
metal-free porphyrins (2H-Ps) in contact with the rutile TiO2 (110) surface. In the absence of …

With their flexible oxidation and spin states, surface-supported metalloporphyrins are
attractive building blocks for tuneable, periodic spin interfaces. A technique to manipulate …

On-surface molecular functionalization paved the way for the stabilization of chelated ions in
different oxidation and spin states, allowing for the fine control of catalytic and magnetic …

The efficiency of interfacial charge transfer for photovoltaic and photocatalytic applications of
metal-tetraphenylporphyrins (M-TPPs) on rutile TiO 2 (110) is governed by the molecular …

On‐surface chemistry holds the potential for ultimate miniaturization of functional devices.
Porphyrins are promising building‐blocks in exploring advanced nanoarchitecture concepts …

The desirable self‐assembly (SA) of repeated 2D stacked layers requires a “holistic
analysis” of three interconnected components: the electrode, the interface, and the …

Stabilizing ordered assemblies of molecules represents the first step towards the
construction of molecular devices featuring hybrid (organic–inorganic) interfaces where …

An important pathway for functionalization of porphyrin-based organic-inorganic structures is
the metalation of porphyrins. Recently, the porphyrin metalation was demonstrated on …

Coordination polymers may be synthesized by linear bridging ligands to metal ions with
conventional chemistry methods (eg in solution). Such complexes can be hardly brought …

A detailed understanding of interfacial electronic properties of organic–inorganic hybrid
junctions is crucial for their technological applications. In case of organic–inorganic hybrid …