Application of (4+ 3) cycloaddition strategies in the synthesis of natural products
(4+ 3) Cycloadditions have been widely applied in synthesis, and in this review article, we
summarize some of the more recent applications, including formal (4+ 3) cycloadditions, in …
summarize some of the more recent applications, including formal (4+ 3) cycloadditions, in …
An overview of synthetic approaches for heterocyclic steroids
Steroids belong to an essential class of bioactive natural products owing to their ability to
enter cell membranes and bind to nuclear and membrane receptors. The steroidal system …
enter cell membranes and bind to nuclear and membrane receptors. The steroidal system …
Gallium (III)‐Catalyzed Three‐Component (4+ 3) Cycloaddition Reactions
X Han, H Li, RP Hughes, J Wu - Angewandte Chemie International Edition, 2012 - infona.pl
Direct approach to indoles: The title reaction generates cyclohepta [b] indole derivatives in a
single step at room temperature (see scheme). Exclusion of air or moisture is not required …
single step at room temperature (see scheme). Exclusion of air or moisture is not required …
Lewis acid catalyzed formal intramolecular [3+ 2] cross-cycloaddition of cyclopropane 1, 1-diesters with alkenes: general and efficient strategy for construction of …
W Zhu, J Fang, Y Liu, J Ren, Z Wang - Angewandte Chemie, 2013 - search.ebscohost.com
Developing efficient and general strategies to construct skeletally complex and diverse
polycyclic skeletons is important for both synthesis of natural products and chemical biology …
polycyclic skeletons is important for both synthesis of natural products and chemical biology …
The versatility of furfuryl alcohols and furanoxonium ions in synthesis
MJ Palframan, G Pattenden - Chemical Communications, 2014 - pubs.rsc.org
Substituted furfuryl alcohols are extraordinarily versatile starting materials in synthesis. They
are precursors to furanoxonium ion intermediates which are implicated in the Piancatelli …
are precursors to furanoxonium ion intermediates which are implicated in the Piancatelli …
Unprecedented Reactivity of γ‐Amino Cyclopentenone Enables Diversity‐Oriented Access to Functionalized Indoles and Indole‐Annulated Ring Structures
C Jagadeesh, B Mondal, S Pramanik… - Angewandte Chemie …, 2021 - Wiley Online Library
Observation of an unexpected, Lewis acid promoted displacement of latent reactive γ‐amino
group on cyclopentenone presented unparalleled opportunity for enone functionalization …
group on cyclopentenone presented unparalleled opportunity for enone functionalization …
Total synthesis of (−)-ambiguine P
J Xu, VH Rawal - Journal of the American Chemical Society, 2019 - ACS Publications
Described is a concise total synthesis of (−)-ambiguine P, a cycloheptane-containing
member of the hapalindole alkaloids. The challenging pentacyclic framework of the natural …
member of the hapalindole alkaloids. The challenging pentacyclic framework of the natural …
[PDF][PDF] Duality of Donor-Acceptor Cyclopropane Reactivity as a Three-Carbon Component in Five-Membered Ring Construction:[3+ 2] Annulation Versus [3+ 2] …
YA Volkova, EM Budynina, AE Kaplun… - Chemistry-A European …, 2013 - chem.msu.ru
The long-standing and continuous interest in efficient synthetic approaches to
cyclopentanoids stems from their value as building blocks in organic chemistry and their …
cyclopentanoids stems from their value as building blocks in organic chemistry and their …
Total Synthesis of (+/−)‐Frondosin B and (+/−)‐5‐epi‐Liphagal by Using a Concise (4+3) Cycloaddition Approach
DR Laplace, B Verbraeken… - … –A European Journal, 2014 - Wiley Online Library
Abstract A recently developed (4+ 3) cycloaddition between dienes and furfuryl alcohols, as
precursors of oxyallyl‐type cations, has been used as a key step in the racemic syntheses of …
precursors of oxyallyl‐type cations, has been used as a key step in the racemic syntheses of …
Zinc‐Catalyzed [4+3] Cycloaddition with Concomitant Furan Annulation: Formation of Cyclohepta[b]Furans
B Song, LH Li, XR Song, YF Qiu… - … A European Journal, 2014 - Wiley Online Library
Abstract A convenient zinc‐promoted [4+ 3] cycloaddition of a carbonyl ene–yne with simple
dienes was first achieved. This reaction provided an efficient strategy to prepare various …
dienes was first achieved. This reaction provided an efficient strategy to prepare various …