High-Pressure Electrochemical Reduction of CO2 to Formic Acid/Formate: Effect of pH on the Downstream Separation Process and Economics

M Ramdin, ART Morrison, M De Groen… - Industrial & …, 2019 - ACS Publications
We use a high-pressure semicontinuous batch electrochemical reactor with a tin-based
cathode to demonstrate that it is possible to efficiently convert CO2 to formic acid (FA) in low …

Simulation and economic analysis of 5-hydroxymethylfurfural conversion to 2, 5-furandicarboxylic acid

C Triebl, V Nikolakis, M Ierapetritou - Computers & chemical engineering, 2013 - Elsevier
Two processes for converting 5-hydroxymethylfurfural (HMF) to 2, 5-furandicarboxylic acid
(FDCA) were designed using literature data together with simplified process simulation …

Reactive extraction of monocarboxylic acids (formic, acetic, and propionic) using tributyl phosphate in green solvents (cyclopentyl methyl ether and 2 …

FN Türk, S Çehreli, N Baylan - Journal of Chemical & …, 2020 - ACS Publications
The separation of monocarboxylic acids (formic, acetic, and propionic) from aqueous
solutions is still a current issue for both scientific and industrial fields. Reactive extraction …

Reactive extraction of bio‐based 3‐hydroxypropionic acid assisted by hollow‐fiber membrane contactor using TOA and Aliquat 336 in n‐decanol

G Burgé, F Chemarin, M Moussa… - Journal of Chemical …, 2016 - Wiley Online Library
BACKGROUND Reactive liquid–liquid extraction is a promising technique for the direct
recovery of carboxylic acids from bioconversion media. This work focused on the …

Experimental and Theoretical Investigations on the Reactive Extraction of Itaconic (2-Methylidenebutanedioic) Acid Using Trioctylamine (N,N-Dioctyloctan-1-amine)

H Uslu, D Datta - Journal of Chemical & Engineering Data, 2015 - ACS Publications
The paper presents the equilibrium distribution study of itaconic acid (also known as 2-
methylidenebutanedioic acid, 0.615 mol· kg–1) between water and trioctylamine (TOA …

Experimental and Theoretical Equilibrium Insights in the Reactive Extraction of Pimelic Acid with Tri-n-octylamine in Natural Solvents

S Pandey, A Jaiswal, A Sohane, DS Patle… - Industrial & …, 2021 - ACS Publications
The theoretical and experimental studies on the reactive extraction of pimelic acid (PA) from
dilute aqueous solutions with tri-n-octylamine (TOA) in three different green and natural …

Realization for rapid extraction of citric acid from aqueous solutions using deep eutectic solvents

Y Baş, M Lalikoglu, A Uthan, E Kordon, A Anur… - Journal of Molecular …, 2024 - Elsevier
Citric acid is highlighted as a valuable chemical in the pharmaceutical and food industries.
We present an extraction technique using hydrophobic deep eutectic solvents (HDES) …

Retarding of electrochemical oxidation of formate on the platinum anode by a coat of Nafion membrane

R Zhang, W Lv, G Li, MA Mezaal, X Li, L Lei - Journal of Power Sources, 2014 - Elsevier
It has been found that the faradaic efficiency is decreasing with the electrolysis time for
electrochemical reduction of CO 2 to formate on a Sn cathode with a Pt anode in an …

Reactive extraction of pimelic (heptanedioic) acid from dilute aqueous solutions using trioctylamine in decan-1-ol

ME Marti, H Zeidan, H Uslu - Fluid Phase Equilibria, 2016 - Elsevier
The present study is on the reactive extraction of pimelic acid (heptanedioic acid) from dilute
aqueous solutions by trioctylamine (TOA) in decan-1-ol. The equilibrium studies were …

Intensification of recovery of formic acid from aqueous stream using reactive extraction with n, n-dioctyloctan-1-amine: effect of diluent and temperature

D Datta, S Kumar - Chemical Engineering Communications, 2013 - Taylor & Francis
The present work is aimed at intensifying the recovery of formic acid from aqueous solution
(industrial waste stream, bio-oil generated stream, and fermentation broth) using reactive …