Direct C–H bond arylation of (hetero) arenes is a very convenient approach for the synthesis
of a wide variety of molecular targets, including compounds of pharmaceutical interest and π …

Synthetically useful functional groups, including ketones, amides, carbamates, carboxylic
acids, aldehydes or ethers, have been identified as weakly coordinating directing groups in …

Catalyzed C–H activation has surfaced as an enabling tool for molecular assembly, with a
plethora of translational applications. The enormous developments toward the utilization of …

The past decades have witnessed rapid development in organic synthesis via catalysis,
particularly the reactions through C–H bond functionalization. Transition metals such as Pd …

Experimental and computational studies provide detailed insight into the selectivity‐and
reactivity‐controlling factors in bifurcated ruthenium‐catalyzed direct C− H arylations and …

Organic syntheses based on the activation of C–H bonds catalysed by transition metals (TM)
are of great interest because new pathways can be designed that were not previously …

In recent years, palladium‐catalyzed direct arylation of (hetero) aromatics with aryl halides
through a C H bond activation has become a popular method for generating carbon …

Pyrrole‐and indole‐fused isocoumarins constitute important structural units in natural
products and pharmacophores, although the direct and selective bifunctionalization of …

Aryl chlorides are readily available at lower cost than the corresponding bromides and
iodides, but are much more challenging as substrates in metal-catalyzed cross-couplings …

The significant number of papers and reviews published in this last decade testifies to the
utility of the transition-metal-catalyzed direct C–H (hetero) arylation reactions of (hetero) …