The pincer platform beyond classical coordination patterns
The pincer platform provides increased stability and often a rigid coordination mode in
transition metal complexes that allows for the incorporation of reactive functional groups in …
transition metal complexes that allows for the incorporation of reactive functional groups in …
Lewis pairing and frustration of group 13/15 elements geometrically enforced by (ace) naphthalene, biphenylene and (thio) xanthene backbones
O Sadek, G Bouhadir, D Bourissou - Chemical Society Reviews, 2021 - pubs.rsc.org
The synthesis, structure, and reactivity of mixed group 13/group 15 compounds (E13= B, Al,
Ga, In, Tl; E15= N, P, Sb, Bi) featuring a rigid (ace) naphthalene or (thio) xanthene backbone …
Ga, In, Tl; E15= N, P, Sb, Bi) featuring a rigid (ace) naphthalene or (thio) xanthene backbone …
Persistent and Predominantly Localized Boron Radical from the Reduction of a Three‐Dimensional Analogue of NHC‐Stabilized Borafluorenium
L Xiang, J Wang, I Krummenacher… - … A European Journal, 2023 - Wiley Online Library
In this contribution, we reported the three‐dimensional (3D) analogues of N‐heterocyclic
carbene (NHC)‐stabilized 9‐borafluorenium and 9‐borafluorene radical. The radical was …
carbene (NHC)‐stabilized 9‐borafluorenium and 9‐borafluorene radical. The radical was …
Theoretical investigations on P-stabilized boryl cation radicals: from the Aufbau principle to SOMO–HOMO conversion
Y Li, Z Ding, Q Mu, J Ren, Q Shen, S Zhang… - Dalton …, 2023 - pubs.rsc.org
We report the characterization of a series of novel phosphinidene-stabilized (P-stabilized)
boryl cation radicals, in which the phosphinidene and boryl are stabilised by iPrNHC …
boryl cation radicals, in which the phosphinidene and boryl are stabilised by iPrNHC …
Ambiguous Role of N→ Sn Coordinated Stannylene: Lewis Base or Acid?
M Aman, L Dostál, Z Růžičková, S Mebs… - …, 2019 - ACS Publications
peri-Substituted naphthalene derivatives 1-BCy2-8-SnL-C10H6 (5), 1-PPh2-8-SnL-C10H6
(6), and 1, 8-(SnL) 2-C10H6 (7)(L= 2, 6-(Me2NCH2) 2C6H3) were prepared. Compounds 5 …
(6), and 1, 8-(SnL) 2-C10H6 (7)(L= 2, 6-(Me2NCH2) 2C6H3) were prepared. Compounds 5 …
A quantum-chemical insight into SOMO–HOMO conversion in phosphorus–boron cation radicals
L Zhang, H Li, Y Zhu, S Zhang - Physical Chemistry Chemical Physics, 2024 - pubs.rsc.org
Organic radicals exhibiting SOMO–HOMO conversion (SHC) electronic configurations have
recently garnered increasing attention due to their exceptional stability and photophysical …
recently garnered increasing attention due to their exceptional stability and photophysical …
B-substituted group 1 phosphides: synthesis and reactivity
M Aman, L Dostál, A Růžička, Z Růžičková… - Dalton …, 2023 - pubs.rsc.org
1-Boryl-8-phosphinonaphthalenes 1-BCy2-8-PCl2-C10H6 (1) and 1-BCy2-8-PPhCl-C10H6
(2) were prepared and used as starting materials for the synthesis of B-substituted …
(2) were prepared and used as starting materials for the synthesis of B-substituted …
Persistent P-Stabilized Boryl Radicals with Bulky Substituents at Boron
AJ Rosenthal, S Mallet-Ladeira, G Bouhadir… - …, 2018 - thieme-connect.com
Two new P-stabilized boryl radicals [Ph 2 P (naph) BAr](Ar= Tip and Ter) have been
prepared and characterized by electron paramagnetic resonance spectroscopy. These …
prepared and characterized by electron paramagnetic resonance spectroscopy. These …
Frustrated Lewis Pair based on a peri‐Substituted Biphenylene Scaffold
F Kutter, E Lork, J Beckmann - Zeitschrift für anorganische und …, 2018 - Wiley Online Library
Starting from 1, 8‐dibromo‐biphenylene,[1‐(bromo) biphenylen‐8‐yl] diphenylphosphine (1)
and [1‐(diphenylphosphanyl) biphenylen‐8‐yl] dimesitylborane (2) were prepared by …
and [1‐(diphenylphosphanyl) biphenylen‐8‐yl] dimesitylborane (2) were prepared by …
Tertiary phosphines: preparation and reactivity
EI Musina, AV Shamsieva, AS Balueva, AA Karasik - 2020 - books.rsc.org
This chapter covers the literature published during 2018 relating to the synthesis and the
reactivity of tertiary phosphines excluding the chemistry of their metal complexes. Although it …
reactivity of tertiary phosphines excluding the chemistry of their metal complexes. Although it …