Probing the structures and bonding of size-selected boron and doped-boron clusters

T Jian, X Chen, SD Li, AI Boldyrev, J Li… - Chemical Society …, 2019 - pubs.rsc.org
Because of their interesting structures and bonding and potentials as motifs for new
nanomaterials, size-selected boron clusters have received tremendous interest in recent …

Understanding boron through size-selected clusters: structure, chemical bonding, and fluxionality

AP Sergeeva, IA Popov, ZA Piazza, WL Li… - Accounts of chemical …, 2014 - ACS Publications
Conspectus Boron is an interesting element with unusual polymorphism. While three-
dimensional (3D) structural motifs are prevalent in bulk boron, atomic boron clusters are …

Planar hexagonal B36 as a potential basis for extended single-atom layer boron sheets

ZA Piazza, HS Hu, WL Li, YF Zhao, J Li… - Nature …, 2014 - nature.com
Boron is carbon's neighbour in the periodic table and has similar valence orbitals. However,
boron cannot form graphene-like structures with a honeycomb hexagonal framework …

Two-dimensional boron monolayer sheets

X Wu, J Dai, Y Zhao, Z Zhuo, J Yang, XC Zeng - ACS nano, 2012 - ACS Publications
Boron, a nearest-neighbor of carbon, is possibly the second element that can possess free-
standing flat monolayer structures, evidenced by recent successful synthesis of single …

Photoelectron spectroscopy of size-selected boron clusters: from planar structures to borophenes and borospherenes

LS Wang - International Reviews in Physical Chemistry, 2016 - Taylor & Francis
Photoelectron spectroscopy (PES) in combination with computational chemistry has been
used systematically over the past decade to elucidate the structures and chemical bonding …

Cobalt-centred boron molecular drums with the highest coordination number in the CoB16 cluster

IA Popov, T Jian, GV Lopez, AI Boldyrev… - Nature …, 2015 - nature.com
The electron deficiency and strong bonding capacity of boron have led to a vast variety of
molecular structures in chemistry and materials science. Here we report the observation of …

All-boron analogues of aromatic hydrocarbons: B17− and B18−

AP Sergeeva, BB Averkiev, HJ Zhai… - The Journal of …, 2011 - pubs.aip.org
We have investigated the structural and electronic properties of the B 17− and B 18− clusters
using photoelectron spectroscopy (PES) and ab initio calculations. The adiabatic electron …

A Photoelectron Spectroscopic and Theoretical Study of B16 and B162−: An All-Boron Naphthalene

AP Sergeeva, DY Zubarev, HJ Zhai… - Journal of the …, 2008 - ACS Publications
The structure and chemical bonding of B16− were studied using ab initio calculations and
photoelectron spectroscopy. Its global minimum is found to be a quasi-planar and elongated …

B 38: an all-boron fullerene analogue

J Lv, Y Wang, L Zhu, Y Ma - Nanoscale, 2014 - pubs.rsc.org
Fullerene-like structures formed by elements other than carbon have long been sought.
Finding all-boron (B) fullerene-like structures is challenging due to the geometrical …

A New Anisotropic Dirac Cone Material: AB2S Honeycomb Monolayer

Y Zhao, X Li, J Liu, C Zhang… - The journal of physical …, 2018 - ACS Publications
Different from the isotropic Dirac cones existing in other two-dimensional (2D) materials,
anisotropic Dirac cones have the merit of anisotropic carrier mobility for applications in …