Metal–organic cages for molecular separations

D Zhang, TK Ronson, YQ Zou, JR Nitschke - Nature Reviews Chemistry, 2021 - nature.com
Separation technology is central to industries as diverse as petroleum, pharmaceuticals,
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …

Assembling metal–organic cages as porous materials

E Sánchez-González, MY Tsang, J Troyano… - Chemical Society …, 2022 - pubs.rsc.org
There is growing interest in metal–organic cages (MOCs) as porous materials owing to their
processability in solution. The discrete molecular character and surface features of MOCs …

Post-synthetic modifications of metal–organic cages

J Liu, Z Wang, P Cheng, MJ Zaworotko… - Nature Reviews …, 2022 - nature.com
Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …

Hierarchical porous metal–organic gels and derived materials: from fundamentals to potential applications

JK Wychowaniec, H Saini, B Scheibe… - Chemical Society …, 2022 - pubs.rsc.org
Metal–organic gels (MOGs) emerged as a novel class of functional soft materials in which
the scaffolding framework is fabricated by metal–ligand coordination in combination with …

The rise of metal–organic polyhedra

S Lee, H Jeong, D Nam, MS Lah, W Choe - Chemical Society Reviews, 2021 - pubs.rsc.org
Metal–organic polyhedra are a member of metal–organic materials, and are together with
metal–organic frameworks utilized as emerging porous platforms for numerous applications …

Permanently microporous metal–organic polyhedra

AJ Gosselin, CA Rowland, ED Bloch - Chemical reviews, 2020 - ACS Publications
As compared to porous network solids, including metal–organic frameworks, covalent–
organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials …

Heterometallic cages: synthesis and applications

LK Moree, LAV Faulkner, JD Crowley - Chemical Society Reviews, 2024 - pubs.rsc.org
High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …

Coordination/metal–organic cages inside out

T Tateishi, M Yoshimura, S Tokuda, F Matsuda… - Coordination Chemistry …, 2022 - Elsevier
Cage-like molecules, assembled by the coordination of multiple metal ions and organic
links, are pushing new frontiers in science due to their design flexibility and the resulting …

Tailor‐Made PdnL2n Metal‐Organic Cages through Covalent Post‐Synthetic Modification

D Luo, ZJ Yuan, LJ Ping, XW Zhu, J Zheng… - Angewandte …, 2023 - Wiley Online Library
Post‐synthetic modification (PSM) is an effective approach for the tailored functionalization
of metal‐organic architectures, but its generalizability remains challenging. Herein we report …

Self‐Healing and Shape Memory Hypercrosslinked Metal‐Organic Polyhedra Polymers via Coordination Post‐Assembly

J Liu, J Li, S Qiao, Z Wang, P Zhang, X Fan… - Angewandte …, 2022 - Wiley Online Library
Coordination‐driven crosslinking networks with reversible and dynamic characteristics are
gaining increasing interest in diverse application fields. Herein, we use a coordination …