Regioselectivity in palladium-catalysed direct arylation of 5-membered ring heteroaromatics

CB Bheeter, L Chen, JF Soulé, H Doucet - Catalysis Science & …, 2016 - pubs.rsc.org
In recent years, palladium-catalysed arylation of heteroaromatics via C–H bond activation
has become a popular method for generating carbon–carbon bonds. For this reaction, a …

Improving the efficiency and sustainability of catalysts for direct arylation polymerization (DArP)

L Ye, BC Thompson - Journal of Polymer Science, 2022 - Wiley Online Library
In the past decade, direct arylation polymerization (DArP) has rapidly developed as a
sustainable synthetic protocol for cost‐effective, atom‐economical preparation of conjugated …

Silver‐catalyzed arylation of (Hetero) arenes by oxidative decarboxylation of aromatic carboxylic acids

J Kan, S Huang, J Lin, M Zhang… - Angewandte Chemie …, 2015 - Wiley Online Library
A long‐standing challenge in Minisci reactions is achieving the arylation of heteroarenes by
oxidative decarboxylation of aromatic carboxylic acids. To address this challenge, the silver …

[图书][B] CH bond activation in organic synthesis

JJ Li - 2015 - books.google.com
CH activation involves any of a wide range of techniques, often using catalysts in which a
carbon to hydrogen covalent bond of an organic compound is cleaved to replace the …

Facile synthesis of 2, 5-disubstituted thiazoles from terminal alkynes, sulfonyl azides, and thionoesters

T Miura, Y Funakoshi, Y Fujimoto, J Nakahashi… - Organic …, 2015 - ACS Publications
A sequential procedure for the synthesis of 2, 5-disubstituted thiazoles from terminal
alkynes, sulfonyl azides, and thionoesters is reported. A copper (I)-catalyzed 1, 3-dipolar …

PdII‐Catalyzed Regio‐ and Enantioselective Oxidative C−H/C−H Cross‐Coupling Reaction between Ferrocenes and Azoles

ZJ Cai, CX Liu, Q Gu, C Zheng, SL You - Angewandte Chemie, 2019 - Wiley Online Library
Asymmetric C− H bond functionalization reaction is one of the most efficient and
straightforward methods for the synthesis of optically active molecules. Herein we disclose …

Property‐Driven Development of Passively Permeable Macrocyclic Scaffolds Using Heterocycles

GJ Saunders, AK Yudin - Angewandte Chemie International …, 2022 - Wiley Online Library
Passive membrane permeability is a fundamental challenge in the development of bioactive
macrocycles. To achieve this objective, chemists have resorted to various strategies, the …

Developing Bis(imino)acenaphthene-Supported N-Heterocyclic Carbene Palladium Precatalysts for Direct Arylation of Azoles

LQ Hu, RL Deng, YF Li, CJ Zeng, DS Shen… - Organometallics, 2018 - ACS Publications
On the basis of the strategy of developing highly efficient protocol for Pd-catalyzed cross-
coupling reactions, a series of bulky bis (imino) acenaphthene (BIAN)-supported Pd-PEPPSI …

General Approach to Five-Membered Nitrogen Heteroaryl C-Glycosides Using a Palladium/Copper Cocatalyzed C–H Functionalization Strategy

S Zhang, YH Niu, XS Ye - Organic letters, 2017 - ACS Publications
A general approach to the synthesis of diverse heteroaryl-C-Δ1, 2-glycosides has been
developed by employing the Pd (OAc) 2/CuI cocatalyzed direct cross-coupling of five …

Palladium-catalyzed template directed C-5 selective olefination of thiazoles

TK Achar, JP Biswas, S Porey, T Pal… - The Journal of …, 2019 - ACS Publications
An efficient method has been developed to afford highly C-5 selective olefination of thiazole
derivatives utilizing a bifunctional template in an intermolecular fashion. Coordinative …