The Pd-catalyzed reaction of an aryl halide with an alkene affords, in most cases, the
corresponding arylalkene. It is usually considered that this reaction, which is called the Heck …

This Account explores the catalytic reduction of dinitrogen by molybdenum complexes that
contain the [HIPTN3N] 3-ligand ([HIPTN3N] 3-=[(HIPTNCH2CH2) 3N] 3-, where HIPT= 3, 5 …

The catalytic transformation of N2 to NH3 by transition metal complexes is of great interest
and importance but has remained a challenge to date. Despite the essential role of …

This review article summarizes efforts to use nitrous oxide (N2O,'laughing gas') as a reagent
in synthetic chemistry. The focus will be on reactions which are carried out in homogeneous …

Triamidoamine ligands [(RNCH2CH2) 3N] 3-in which R is a bulky substituent, can bind to a
variety of transition metals (or main group elements1) in oxidation states 3+ or higher. They …

Turning a disadvantage to an advantage: The rather disappointing reactivity of the metal–
nitrogen bond in comparison to the metal–carbon bond resulted in the neglect of …

Deprotonation of [U (TrenTIPS)(NH2)](1)[TrenTIPS= N (CH2CH2NSiPri3) 3] with
organoalkali metal reagents MR (M= Li, R= But; M= Na–Cs, R= CH2C6H5) afforded the …

The redox series [Ir n (NH x)(PNP)](n= II–IV, x= 3–0; PNP= N (CHCHP t Bu2) 2) was
examined with respect to electron, proton, and hydrogen atom transfer steps. The …

Group-and atom-transfer is an attractive reaction class for the preparation of value-added
organic substrates. Despite a wide variety of known early-transition metal oxo and imido …

The dilithium salts of N, N ', N ''-tris (trimethylsilyl) diethylenetriamine (1), N-methyl-N ', N ''-bis
(trimethylsilyl) diethylenetriamine (2), and N-methyl-N ', N ''-bis (diisopropyl) …