Selective deprotection of silyl ethers
RD Crouch - Tetrahedron, 2013 - Elsevier
Reactions, which permit the selective deprotection of one silyl-protected alcohol in the
presence of another are reviewed. This review covers examples reported in the literature …
presence of another are reviewed. This review covers examples reported in the literature …
Role of Lewis‐base‐coordinated halogen (I) intermediates in organic synthesis: the journey from unstable intermediates to versatile reagents
The widespread use of halogen‐based reagents in organic synthesis is well known.
Hypervalent halogens (oxidation states III and V) have been explored to a significant extent …
Hypervalent halogens (oxidation states III and V) have been explored to a significant extent …
A Facile, Catalytic, and Environmentally Benign Method for Selective Deprotection of tert-Butyldimethylsilyl Ether Mediated by Phosphomolybdic Acid Supported on …
GD Kishore Kumar, S Baskaran - The Journal of Organic …, 2005 - ACS Publications
An environmentally benign PMA supported on SiO2 is found to be an efficient catalyst for the
chemoselective deprotection of TBDMS ethers under very mild conditions. Various labile …
chemoselective deprotection of TBDMS ethers under very mild conditions. Various labile …
Recent Progress in the Use of N-Halo Compounds in Organic Synthesis
H Veisi, R Ghorbani-Vaghei… - Organic Preparations and …, 2011 - Taylor & Francis
The exploitation of reagents for the development new synthetic methods is an art and
constitutes a challenging process in organic chemistry. Consequently, considerable efforts …
constitutes a challenging process in organic chemistry. Consequently, considerable efforts …
Highly chemoselective esterification reactions and Boc/THP/TBDMS discriminating deprotections under Samarium (III) Catalysis
P Gopinath, S Nilaya, KM Muraleedharan - Organic Letters, 2011 - ACS Publications
Highly Chemoselective Esterification Reactions and Boc/THP/TBDMS Discriminating
Deprotections under Samarium(III) Catalysis | Organic Letters ACS ACS Publications C&EN …
Deprotections under Samarium(III) Catalysis | Organic Letters ACS ACS Publications C&EN …
A novel, chemoselective and efficient microwave-assisted deprotection of silyl ethers with selectfluor
A novel microwave-assisted, chemoselective and efficient method for the cleavage of silyl
ethers (aliphatic and aromatic) catalyzed by Selectfluor is reported. A wide range of TBS …
ethers (aliphatic and aromatic) catalyzed by Selectfluor is reported. A wide range of TBS …
A mild, efficient, and selective deprotection of tert-butyldimethylsilyl (TBDMS) ethers using dicationic ionic liquid as a catalyst
Selective deprotection of alkyl TBDMS ether in the presence of phenolic TBDMS ether using
dicationic ionic liquid [tetraEG (mim) 2][OMs] 2 as a homogeneous catalyst showed …
dicationic ionic liquid [tetraEG (mim) 2][OMs] 2 as a homogeneous catalyst showed …
A high loading sulfonic acid-functionalized ordered nanoporous silica as an efficient and recyclable catalyst for chemoselective deprotection of tert-butyldimethylsilyl …
A high loading sulfonic acid-functionalized ordered nanoporous silica efficiently catalyzes
the deprotection of a variety of alcoholic TBDMS (tert-butyldimethylsilyl) ethers in methanol …
the deprotection of a variety of alcoholic TBDMS (tert-butyldimethylsilyl) ethers in methanol …
Esterification of Aryl/Alkyl Acids Catalysed by N-bromosuccinimide under Mild Reaction Conditions
N-halosuccinimides (NXSs) are well-known to be convenient, easily manipulable and low-
priced halogenation reagents in organic synthesis. In the present work, N-bromosuccinimide …
priced halogenation reagents in organic synthesis. In the present work, N-bromosuccinimide …
Regioselective Silylation of N-Phthaloylchitosan with TBDMS and TBDPS Groups
A Binette, J Gagnon - Biomacromolecules, 2007 - ACS Publications
N-Phthaloylchitosan represents a key intermediate for the regioselective modification of
chitosan in organic media. Chemoselective protection of primary alcohols on N …
chitosan in organic media. Chemoselective protection of primary alcohols on N …