Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013 - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

Highly energetic compositions based on functionalized carbon nanomaterials

QL Yan, M Gozin, FQ Zhao, A Cohen, SP Pang - Nanoscale, 2016 - pubs.rsc.org
In recent years, research in the field of carbon nanomaterials (CNMs), such as fullerenes,
expanded graphite (EG), carbon nanotubes (CNTs), graphene, and graphene oxide (GO) …

Carbene additions to fullerenes

M Yamada, T Akasaka, S Nagase - Chemical Reviews, 2013 - ACS Publications
Carbon is the most prominent element of state-of-the-art nanoscience. Kroto, Curl, and
Smalley were awarded the Nobel Prize in Chemistry in 1996 for discovery of fullerenes. 1− 4 …

Noble gas endohedral fullerenes

S Jalife, J Arcudia, S Pan, G Merino - Chemical Science, 2020 - pubs.rsc.org
This review focuses on the available experimental and theoretical investigations on noble
gas (Ng) endohedral fullerenes, addressing essential questions related to the mutual effects …

DFT studies of single and multiple alkali metals doped C24 fullerene for electronics and nonlinear optical applications

N Kosar, H Tahir, K Ayub, T Mahmood - Journal of Molecular Graphics and …, 2021 - Elsevier
The geometric, electronic and nonlinear properties of exohedral and endohedral single and
multiple alkali metal (Li, Na and K) atom doped C 24 fullerene are studied. First, the most …

The role of aromaticity in determining the molecular structure and reactivity of (endohedral metallo) fullerenes

M Garcia-Borras, S Osuna, JM Luis, M Swart… - Chemical Society …, 2014 - pubs.rsc.org
The encapsulation of metal clusters in endohedral metallofullerenes (EMFs) takes place in
cages that in most cases are far from being the most stable isomer in the corresponding …

Endohedral Metallofullerenes Based on Spherical Ih-C80 Cage: Molecular Structures and Paramagnetic Properties

T Wang, C Wang - Accounts of Chemical Research, 2014 - ACS Publications
Fullerenes are carbon cages assembled from fused hexagons andpentagons that have
closed networks and conjugated π systems. The curve of the fullerene structure requires that …

Exohedral functionalization of endohedral metallofullerenes: Interplay between inside and outside

P Jin, Y Li, S Magagula, Z Chen - Coordination Chemistry Reviews, 2019 - Elsevier
Endohedral metallofullerenes (EMFs) are fullerene cages enclosing various metallic
species. The functionalization of EMFs has remarkably blossomed in recent years, in …

Kinetic Study of the Diels–Alder Reaction of Li+@C60 with Cyclohexadiene: Greatly Increased Reaction Rate by Encapsulated Li+

H Ueno, H Kawakami, K Nakagawa… - Journal of the …, 2014 - ACS Publications
We studied the kinetics of the Diels–Alder reaction of Li+-encapsulated [60] fullerene with 1,
3-cyclohexadiene and characterized the obtained product,[Li+@ C60 (C6H8)](PF6–) …

Polarizability as a landmark property for fullerene chemistry and materials science

DS Sabirov - Rsc Advances, 2014 - pubs.rsc.org
The review summarizes data on dipole polarizability of fullerenes and their derivatives,
covering the most widespread classes of fullerene-containing molecules (fullerenes …