Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis

MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021 - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

Radical-mediated rearrangements: past, present, and future

X Wu, Z Ma, T Feng, C Zhu - Chemical Society Reviews, 2021 - pubs.rsc.org
Rearrangement reactions, one of the most significant transformations in organic chemistry,
play an irreplaceable role in improving synthetic efficiency and molecular complexity …

Programmable late-stage functionalization of bridge-substituted bicyclo [1.1. 1] pentane bis-boronates

Y Yang, J Tsien, R Dykstra, SJ Chen, JB Wang… - Nature …, 2024 - nature.com
Modular functionalization enables versatile exploration of chemical space and has been
broadly applied in structure–activity relationship (SAR) studies of aromatic scaffolds during …

Boron, silicon, nitrogen and sulfur-based contemporary precursors for the generation of alkyl radicals by single electron transfer and their synthetic utilization

V Corcé, C Ollivier, L Fensterbank - Chemical Society Reviews, 2022 - pubs.rsc.org
Recent developments in the use of boron, silicon, nitrogen and sulfur derivatives in single-
electron transfer reactions for the generation of alkyl radicals are described. Photoredox …

Boryl Radical Activation of Benzylic C–OH Bond: Cross-Electrophile Coupling of Free Alcohols and CO2 via Photoredox Catalysis

WD Li, Y Wu, SJ Li, YQ Jiang, YL Li… - Journal of the …, 2022 - ACS Publications
A new strategy for the direct cleavage of the C (sp3)–OH bond has been developed via
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …

Evolution and Future of Hetero‐and Hydro‐Trifluoromethylations of Unsaturated C− C Bonds

S Kawamura, P Barrio, S Fustero… - Advanced Synthesis …, 2023 - Wiley Online Library
The difunctionalizative trifluoromethylation of unsaturated C− C bonds is a highly useful and
efficient method for the synthesis of trifluoromethyl compounds with attractive architectures …

Three-Component Photochemical 1, 2, 5-Trifunctionalizations of Alkenes toward Densely Functionalized Lynchpins

F Paulus, C Stein, C Heusel, TJ Stoffels… - Journal of the …, 2023 - ACS Publications
Radical remote 1, n-difunctionalization reactions (n> 2) of alkenes are powerful tools to
efficiently introduce functional groups with selected distances into target molecules. Among …

The impact of boron hybridisation on photocatalytic processes

A Marotta, CE Adams, JJ Molloy - Angewandte Chemie, 2022 - Wiley Online Library
Recently the fruitful merger of organoboron chemistry and photocatalysis has come to the
forefront of organic synthesis, resulting in the development of new technologies to access …

Decarboxylation of β-boryl NHPI esters enables radical 1,2-boron shift for the assembly of versatile organoborons

Y Guo, X Wang, C Li, J Su, J Xu, Q Song - Nature Communications, 2023 - nature.com
Abstract In recent years, numerous 1, 2-R shift (R= aliphatic or aryl) based on
tetracoordinate boron species have been well investigated. In the contrary, the …

Ir‐Catalyzed Enantioselective Synthesis of gem‐Diborylalkenes Enabled by 1,2‐Boron Shift

JF Ge, XZ Zou, XR Liu, CL Ji, XY Zhu… - Angewandte Chemie …, 2023 - Wiley Online Library
Asymmetric cross‐couplings based on 1, 2‐carbon migration from B‐ate complexes have
been developed efficiently to access valuable organoboronates. However, enantioselective …