Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis
MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021 - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …
Radical-mediated rearrangements: past, present, and future
X Wu, Z Ma, T Feng, C Zhu - Chemical Society Reviews, 2021 - pubs.rsc.org
Rearrangement reactions, one of the most significant transformations in organic chemistry,
play an irreplaceable role in improving synthetic efficiency and molecular complexity …
play an irreplaceable role in improving synthetic efficiency and molecular complexity …
Programmable late-stage functionalization of bridge-substituted bicyclo [1.1. 1] pentane bis-boronates
Modular functionalization enables versatile exploration of chemical space and has been
broadly applied in structure–activity relationship (SAR) studies of aromatic scaffolds during …
broadly applied in structure–activity relationship (SAR) studies of aromatic scaffolds during …
Boron, silicon, nitrogen and sulfur-based contemporary precursors for the generation of alkyl radicals by single electron transfer and their synthetic utilization
V Corcé, C Ollivier, L Fensterbank - Chemical Society Reviews, 2022 - pubs.rsc.org
Recent developments in the use of boron, silicon, nitrogen and sulfur derivatives in single-
electron transfer reactions for the generation of alkyl radicals are described. Photoredox …
electron transfer reactions for the generation of alkyl radicals are described. Photoredox …
Boryl Radical Activation of Benzylic C–OH Bond: Cross-Electrophile Coupling of Free Alcohols and CO2 via Photoredox Catalysis
WD Li, Y Wu, SJ Li, YQ Jiang, YL Li… - Journal of the …, 2022 - ACS Publications
A new strategy for the direct cleavage of the C (sp3)–OH bond has been developed via
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …
Evolution and Future of Hetero‐and Hydro‐Trifluoromethylations of Unsaturated C− C Bonds
S Kawamura, P Barrio, S Fustero… - Advanced Synthesis …, 2023 - Wiley Online Library
The difunctionalizative trifluoromethylation of unsaturated C− C bonds is a highly useful and
efficient method for the synthesis of trifluoromethyl compounds with attractive architectures …
efficient method for the synthesis of trifluoromethyl compounds with attractive architectures …
Three-Component Photochemical 1, 2, 5-Trifunctionalizations of Alkenes toward Densely Functionalized Lynchpins
F Paulus, C Stein, C Heusel, TJ Stoffels… - Journal of the …, 2023 - ACS Publications
Radical remote 1, n-difunctionalization reactions (n> 2) of alkenes are powerful tools to
efficiently introduce functional groups with selected distances into target molecules. Among …
efficiently introduce functional groups with selected distances into target molecules. Among …
The impact of boron hybridisation on photocatalytic processes
A Marotta, CE Adams, JJ Molloy - Angewandte Chemie, 2022 - Wiley Online Library
Recently the fruitful merger of organoboron chemistry and photocatalysis has come to the
forefront of organic synthesis, resulting in the development of new technologies to access …
forefront of organic synthesis, resulting in the development of new technologies to access …
Decarboxylation of β-boryl NHPI esters enables radical 1,2-boron shift for the assembly of versatile organoborons
Y Guo, X Wang, C Li, J Su, J Xu, Q Song - Nature Communications, 2023 - nature.com
Abstract In recent years, numerous 1, 2-R shift (R= aliphatic or aryl) based on
tetracoordinate boron species have been well investigated. In the contrary, the …
tetracoordinate boron species have been well investigated. In the contrary, the …
Ir‐Catalyzed Enantioselective Synthesis of gem‐Diborylalkenes Enabled by 1,2‐Boron Shift
JF Ge, XZ Zou, XR Liu, CL Ji, XY Zhu… - Angewandte Chemie …, 2023 - Wiley Online Library
Asymmetric cross‐couplings based on 1, 2‐carbon migration from B‐ate complexes have
been developed efficiently to access valuable organoboronates. However, enantioselective …
been developed efficiently to access valuable organoboronates. However, enantioselective …