One-Step Synthesis of Ag–Cu Bimetallic Nanoparticles on p-Si Photoelectrodes for Solar-Driven CO2 Reduction

HA Chaliyawala, S Bastide… - ACS Applied Energy …, 2023 - ACS Publications
In the present work, we report the one-step synthesis of Ag x Cu100–x bimetallic
nanoparticles (NPs) on p-type silicon (p-Si) supports and their application as photocathodes …

Effects of bubbles on the electrochemical behavior of hydrogen-evolving Si microwire arrays oriented against gravity

PA Kempler, RH Coridan, NS Lewis - Energy & Environmental Science, 2020 - pubs.rsc.org
The size-distribution, coverage, electrochemical impedance, and mass-transport properties
of H2 gas-bubble films were measured for both planar and microwire-array platinized n+-Si …

Si Microwire-Array Photocathodes Decorated with Cu Allow CO2 Reduction with Minimal Parasitic Absorption of Sunlight

PA Kempler, MH Richter, WH Cheng… - ACS Energy …, 2020 - ACS Publications
High loadings of Cu were integrated on the light-facing side of Si microwire arrays used
under simulated sunlight for the photoelectrochemical reduction of CO2 (aq) to …

Spontaneous mesostructure formation produces optically transmissive Ni–P films that are catalytically active for the photoelectrochemical hydrogen evolution reaction

ZP Ifkovits, JT Reed, PA Kempler, MC Meier… - Sustainable Energy & …, 2023 - pubs.rsc.org
Ni–P films that are catalytically active for the hydrogen-evolution reaction were
electrodeposited onto photoactive Si substrates between 20° C and 80° C from an aqueous …

Primary Corrosion Processes for Polymer-Embedded Free-Standing or Substrate-Supported Silicon Microwire Arrays in Aqueous Alkaline Electrolytes

KM Kennedy, PA Kempler, M Cabán-Acevedo… - Nano Letters, 2021 - ACS Publications
Solar fuel devices have shown promise as a sustainable source of chemical fuels. However,
long-term stability of light absorbing materials remains a substantial barrier to practical …

Spontaneous Formation of> 90% Optically Transmissive, Electrochemically Active CoP Films for Photoelectrochemical Hydrogen Evolution

PA Kempler, HJ Fu, ZP Ifkovits… - The Journal of …, 2019 - ACS Publications
Earth-abundant catalysts for the hydrogen-evolution reaction require increased mass
loadings, relative to Pt films, to achieve comparable activity and stability in acidic …

Enhanced Stability and Efficiency for Photoelectrochemical Iodide Oxidation by Methyl Termination and Electrochemical Pt Deposition on n-Type Si Microwire Arrays

S Ardo, EA Santori, HS Emmer, RL Grimm… - ACS Energy …, 2019 - ACS Publications
Arrays of Si microwires doped n-type (n-Si) and surface-functionalized with methyl groups
have been used, with or without deposition of Pt electrocatalysts, to photoelectrochemically …

Final Science Report of the Joint Center for Artificial Photosynthesis (JCAP)

X Amashukeli, HA Atwater, JA Haber, FA Houle - 2023 - osti.gov
The Joint Center for Artificial Photosynthesis (JCAP) was designated as the US Department
of Energy (DOE) Fuels from Sunlight Energy Innovation Hub on July 22, 2010, and began …

[图书][B] Renewable Energy Generation and Storage: From Microwires to Macro-Energy Systems

KM Kennedy - 2021 - search.proquest.com
Anthropogenic greenhouse gas emissions must reach net-zero quickly in order to meet the
Paris Agreement goal of no more than 2 C of warming, which will require decarbonizing the …

[图书][B] High-Aspect Ratio Structures in Light-Absorbers and Electrocatalysts for Solar Fuels Devices

PA Kempler - 2020 - search.proquest.com
Solar fuels devices produce hydrogen fuel from water and sunlight and address a critical
societal need for inexpensive, long-duration energy storage. Such devices are prepared …