Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

We report hyperpolarized Xe signal advancement by metal-organic framework (MOF)
entrapment (Hyper-SAME) in aqueous solution. The 129Xe NMR signal is drastically …

The selective separation of structurally similar aliphatic/aromatic hydrocarbons is an
essential goal in industrial processes. In this study, we report the synthesis of a water …

This paper presents a comprehensive review of the recent advances in xenon-129 nuclear
magnetic resonance (NMR) measurements. In the past thirty years, 129 Xe NMR has proved …

Chemical separations are expensive, consuming 10–15% of humanity's global energy
budget. Many current separation methods employ thermal energy for distillation, often …

Chemical purifications are critical processes across many industries, requiring 10–15% of
humanity's global energy budget. Coordination cages are able to catch and release guest …

Here we report the subcomponent self‐assembly of a truxene‐faced Zn4L4 tetrahedron,
which is capable of binding the smallest hydrocarbons in solution. By deliberately …

Guest capture and release are important properties of self-assembling nanostructures. Over
time, a significant fraction of guests might engage in short-lived states with different …

We report the construction of three structurally distinct self-assembled architectures:
FeII12L12 pseudoicosahedron 1, FeII2L3 helicate 2, and FeII4L4 tetrahedron 3, formed from …

Here we demonstrate how the hydrogen-bonding ability of a BINOL-based dialdehyde
subcomponent dictated the stereochemical outcome of its subsequent self-assembly into …